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free state
The molecular motional correlation times of two pairs of protons, H-1a/H-1b and H-2/H-3, in the bound state at T = 298 K were 11.7 and 9.46 ns respectively, while they were 27.7 and 35.2 ps in the free state.
      
However, the glycolaldehyde cannot be found the free state because it condenses with another glycolaldehyde residue formed in the course of the cleavage of another ketosubstrate molecule yielding erythrulose.
      
In an associate, a significant fraction of poly(ethylene glycol) fragments incorporated into micelles is in the free state, i.e., these fragments are not bound with a polymer chain.
      
It is shown that bilirubin is adsorbed on the surface of all these sorbents only in the free state.
      
Effect of decomposition of a gas hydrate on the gas recovery from a reservoir containing hydrate and gas in the free state
      
Hydrocarbons are transferred from fixed the state in basaltic glass into the free state in palagonites practically without any changes.
      
In experiments on crosslinking of the BamHI MTase subunits, it was shown that the enzyme in a free state exists as a dimer.
      
Most of these peptides were shown to exhibit the immunogenic activity in a free state.
      
Structural parameters and IR spectra of p-hydroxyphenyldiazonium cation and its conjugated base and of their monohydrates in the free state and in aqueous solution were calculated by the B3LYP/6-311G** method.
      
Atomic charges and structural parameters of borabenzene, pyridine and their adduct in free state, in liquid argon and in tetrahydrofuran are calculated by the quantum-chemical method B3LYP/6-311G(3d5f7,p) >amp;amp; PCM.
      
The probability of electron tunneling from a bound state into a free state in crossed ac electric and dc magnetic fields is calculated in the quasiclassical approximation.
      
When the direction of the field is reversed, flux penetration is not possible and a flux-free state exists in the junction.
      
This matrix element determines the transition probability of electron photoemission from a one-electron orbital with symmetry γμ to a free state.
      
It is found that the C20 skeleton in the free state is described by space group D3d; in the case where C20 is placed into the C80(Ih) fullerene field, the space group of C20 is raised to Ih due to isomerization.
      
Critical magnetic field of the vortex-free state in NbC thin films and prospects for its observation in MgB2
      
It is revealed that the critical fields exhibit strong anisotropy due to the vortex-free state of the film in a magnetic field aligned parallel to its surface.
      
The dependence Hc‖(T) agrees quantitatively with the concepts of microscopic theory on the vortex-free state of a thin film of a clean superconductor in the temperature range below Tc.
      
Clusters possessing low stability in the free state or completely unstable clusters tending to dissociate leave the surface more readily.
      
The magnitude of mechanical stresses induced by this moment in the medium is found to change in a stepwise manner upon a "phase transition" of the particle from the bound to the free state.
      
The quantity which keeps its value, when the variations of the energy of the system are calculated, is not the area of the deformed membrane, but its area in the flat tension free state.
      
 

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