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2-dichloroethane
Using 1,2-dichloroethane as solvent, triphenylphosphine as reducer, and triethylamine as catalyst, n(I): n(II): n(triphenylphosphine)51.0: 1.0: 1.0, the product was obtained at room temperature in 98.1% yield.
      
The voltammetric behavior of silver at the water/nitrobenzene and water/1,2-dichloroethane interfaces was studied in the presence of diphenylthiourea and O,O-dihexyl dithiophosphates.
      
The effect of several solvents on the selectivity of the free radical chlorination of 1,1-dichloroethane and 1-chloropropane is studied.
      
The decomposition of 1,2-dichloroethane and chlorobenzene on nickel-alumina, cobalt-alumina, and iron-alumina catalysts at 400-600°C was studied.
      
The addition of hydrogen to the reaction mixture was found to dramatically decrease the rate of carbon deposition in the decomposition of 1,2-dichloroethane because of the intense hydrogenation of intermediates that are graphite precursors.
      
Different trends exist for aromatic and nonaromatic solvents for changes in the activation energies of the competitive chlorination of tetrachloroethene and 1,2-dichloroethane depending on the solvent concentration.
      
The recovery of platinum(IV) from hydrochloric acid solutions containing an excess amount ofiron(III) with liquid tri-n-octylamine-1'2-dichloroethane membranes under conditions of galvanostatic dialysiswas studied.
      
The possibility of thermochemical regeneration of an industrial batch of a spent and partially deactivated catalyst to improve its activity and selectivity in oxidative chlorination of ethylene to give 1,2-dichloroethane was studied.
      
Extraction of silver(I) from nitric acid solution by electrodialysis with liquid membranes containing di(2-ethylhexyl) hydrogen phosphate with addition of tri-n-octylamine in 1,2-dichloroethane is studied.
      
Potential-Dependent Adsorption of Transferring Ions Having Asymmetric Charge Distribution at the 1,2-Dichloroethane|Water Interf
      
The kinetics of the transfer of Erythrosine B dianions (EB2-) and Eosin Y dianions (EY2-) across the 1,2-dichloroethane|water interface, studied using ac-modulated voltfluorometry, is compared with that of Rose Bengal dianions (RB2-).
      
Kinetics of facilitated proton transfer by polyether 18-crown-6 across the water-1,2-dichloroethane interface
      
The kinetics of facilitated proton transfer by polyether 18-crown-6 across the water-1,2-dichloroethane interface has been investigated by cyclic voltammetry and ac impedance.
      
Electrochemical properties of aniline in 1,2-dichloroethane are investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and in situ UV-vis spectroelectrochemistry.
      
The molar reaction volume is strongly solvent-dependent, cm3/mol: -11.3±1.0 in o-xylene, -14.9±1.0 in toluene, -20.6±1.5 in 1,2-dichloroethane, -22.6±1.5 in ethyl acetate, and -24.2±1.5 in acetonitrile.
      
Partial molar volumes and heats of solution were determined for gallium chloride in benzene, toluene, o-xylene, mesitylene, 1,2-dichloroethane, ethyl acetate, acetonitrile, and 1,4-dioxane.
      
The kinetics of heterolysis of t-BuCl in sulfolane, PhCN, PhNO2, acetophenone, cyclohexanone, chloroform, and 1,2-dichloroethane at 30-50°C were studied by the verdazyl method.
      
Reaction of H2PtCl6 with 18-crown-6 and dibenzo-18-crown-6 in 1,2-dichloroethane and acetonitrile
      
Reaction of PtCl4 with 18-crown-6 in aprotic solvents (Nitromethane, acetonitrile, and 1,2-dichloroethane)
      
Specific features of the reaction of anhydrous PtCl4 with 18-crown-6 in anhydrous solvents with different donor and solvating abilities, such as nitromethane, acetonitrile, and 1,2-dichloroethane, under an inert atmosphere are studied.
      
 

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