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    An Unified Retention Model of Solute for Binary-solvent Systems in Liquid Chromatography
    在二元溶剂体系中液相色谱的一个溶质统一保留模型
    Review,Analysis and Prospect of Structure Preserving Models in Power Systems
    电力系统结构保留模型的回顾、分析和展望
    The strict Lyapunov energy function is constructed for the network structure preserving model and load model with the steady voltage character.
    基于网络结构保留模型,发电机采用二阶经典模型,负荷计及静态电压特性,构造了满足严格Lyapunov稳定性的能量函数。
    A new characterization parameter in liquid chromatography, the stoichiometric parameter Z of stoichiometric displacement model for retention of solute, is suggested.
    文中首次提出了液相色谱中溶质计量置换保留模型中的计量参数Z可作为液相色谱的一个新的表征参数。
    Based on the stoichiometric displacement model for retention in liquid chromatography, two linear relations for the plots of lgI( constant relating to the affinity of 1mol solute to stationary phase) and Z (moles of displacing agent released as 1mol solute is adsorbed versus reciprocal of absolute temperature)in reversed-phase high proformance liquid chrbmatogrpahy (RP-HPLC) were theoretically derived, respectively.
    依据液相色谱中溶质计量置换保留模型,从理论上分别推导出了在反相高效液相色谱(RP-HPLC)中lgI(与1mol溶质对固定相的亲合势有关的常数)和Z(对应于1mol溶质被固定相吸附时释放出置换剂的摩尔数)对绝对温度导数的线性关系式发现非极性与极性小分子溶质的lgI和Z均具有热力学平衡常数的特征.
    According to stoichiometric displacement model for retention (SDM - R), the covergent phenomenon of homologues in reversed - phase liquid chromatography (RPLC) was studied.
    以液相色谱中的溶质计量置换保留模型(SDM-R)为理论基础,从热力学角度进一步对反相液相色谱中同系物的收敛性进行了研究.
    Results:The SS levels of hypothalamus、stomach、intestines in the pituitaryectomied rats of spleen deficiency were higher than those of the normal control and model group with pituitary(P<0.01).
    结果:脾虚大鼠去脑垂体后,下丘脑、胃、肠组织中的SS含量明显高于同期正常健康对照和垂体保留模型对照(P<0.01);
    Research on Structure Preserving Models and Construction of Bounding Functions in Power Systems
    电力系统结构保留模型及上界函数法暂态稳定域构建的研究
    Study on Determination of Anion by Single-column LPIC and Modeling of Ion Chromatography Retention
    低压离子色谱单柱法测定阴离子及建立离子色谱保留模型的研究
    Researches on the Retention Model of Protein and Relation among the Model Parameters in the Hydrophobic Interaction Chromatography
    蛋白质在疏水作用色谱上的保留模型及其模型参数间关系的研究
    Improvement of the Retention Model in Reversed Phase-High Performance Liquid Chromatography and Prediction of the Retention of Ferrocene Derivatives
    一种色谱保留模型的改进及二茂铁衍生物保留值的预测
    It was the first time to establish mathematics model to describe their retention behavior on PHPLC system, which can be used to guide the optimization of mobile phase.
    根据色谱保留理论首次建立了制备色谱流动相组成与保留因子之间关系的保留模型,用于优化色谱分离参数;
    In chapter 2, the history and its main branches of SPM are reviewed at first, then the SPM was analyzed and induced according to the relevant theories, ultimately the research field of SPM was also prospected.
    论文第二章中回顾了自80年代开始提出的几种主流的结构保留模型,然后对它们进行了理论分析和归纳,并且通过几种不同的理论和方法找出了它们之间的本质联系,最后对其进行了总结和展望。
    It was found that the retention of aromatic alcohol homologues and proteins obeys to the stoichimetric displacement model for retention (SDM-R) in the temperature range of 0-SO癈 and 0-50癈, respectively, and the former also conforms to the homologue rule.
    发现芳香醇同系物在0~80℃温度范围内及不同盐的流动相中都遵循计量置换保留模型和同系物规律,蛋白质分子在0~50℃温度范围内的保留行为也遵循计量置换保留模型
    2 The results of the QSRR of saturated aliphatic alcohols on the phenylmethylpolysiloxane stationary phases show that the retention indexes are related to the ability of the solutes to undergo London force, charge transfer interaction and inductive interaction.
    2.建立了饱和脂肪醇在苯基甲基聚硅氧烷上的定量结构与其色谱保留的模型,结果表明,醇类化合物的保留指数与其参与色散力、德拜力和电子传递作用均相关。
    3. The results of the QSRR of the esters on the polysiloxane stationary phases show that the retention indexes are related to the ability of the solutes to undergo London force, charge transfer interaction and inductive interaction.
    3.建立了酯类化合物在聚硅氧烷上的定量结构与其色谱保留的模型,结果表明,醇类化合物的保留指数与其参与色散力、德拜力和电子传递作用均相关。
    4. The results of the QSRR of the CTPC as stationary phase show that the retention coefficients are related to the ability of the solutes to undergo London force, chargetransfer interaction and inductive interaction.
    4.建立了纤维素三苯氨基甲酸酯作气相色谱固定相的定量结构与其色谱保留模型,结果表明,各化合物的保留指数与其参与色散力、德拜力和电子传递作用均相关。
    5. The results of the QSRR of the sulphurets in the gasoline show that the retention indexes are related to not only the solute and the stationary phase, but also the column temperature.
    5.建立了汽油中含硫化合物的定量结构与其色谱保留的模型,结果表明,化合物的色谱保留不仅和溶质、固定相有关,而且还和柱温有关。
    6. The results of the QSRR of the liquid chromatographic retention indexes of the paraffins show that the retention coefficients are related to the ability of the solutes to undergo London force, charge transfer interaction, and the liquid chromatographic retention coefficients of the aromatic hydrocarbons are related to the ability of the solutes to undergo London force.
    6.分别建立了烷烃和芳香烃化合物的分子结构和液相色谱保留的模型,结果表明,烷烃化合物的液相色谱保留与溶质参与色散力和电子传递作用的能力有关;
    7. The results of the QSRR of the chirai carboxvlic acid on the chiral stationary phase show that the retention coefficients are related to not only the ability of the solutes to undergo London force, charge transfer interaction, inductive interaction, but also logP.
    7.建立了手性苯丙酸在手性固定相上的定量结构和色谱保留模型,结果表明,其色谱保留不仅与溶质参与色散力、德拜力和电子传递作用相关,而且还和logP相关。
 

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