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激基缔合物荧光
相关语句
  excimer fluorescence
    STUDIES ON THE EXCIMER FLUORESCENCE OF BUTADIENE-STYRENE COPOLYMER OF LOW STYRENE CONTENT
    低苯乙烯含量的丁二烯-苯乙烯共聚物的激基缔合物荧光研究
短句来源
    STUDY OF EXCIMER FLUORESCENCE SPECTRA OF POLYPHENYLENE SULFIDE SULFONE
    聚苯硫醚砜激基缔合物荧光光谱的研究
短句来源
    The pyrene excimer fluorescence was observed in n-lauryltriphenylphosphonium bromide or n-cetyltrithenylphosphonium bromide micellar solution and the microviscosity in micellar core of the above-mentioned two phosphoniums was estimated to be 229 cP and 241 cP (23℃),respectively, by using the relation between the probability of excimer formation and the viscosity.
    在正十二烷基三苯基溴化鏻及正十六烷基三苯基溴化鏻胶束溶液中观察到了芘的激基缔合物荧光,利用激基缔合物形成几率与粘度的关系估计了这两种鏻盐胶束内核微粘度分别为229 cP和241 cP(23℃)。
短句来源
    Study on Molecular Configuration of Poly(Styrene b methyl methacrylate) in Solution by Excimer Fluorescence Technique
    用激基缔合物荧光研究聚苯乙烯-聚甲基丙烯酸甲酯嵌段共聚物在溶液中的分子构型
短句来源
    At very low concentration pyrenyl alkyl ketones with long chain show excimer fluorescence and the monomer fluorescence is blue shifted, indicating aggregate formation Saturated hydrocarbons with long chain coaggregate with these ketones.
    在浓度非常低的情况下,长链芘基烷基酮发射激基缔合物荧光,单体荧光也明显蓝移,表明芘基烷基酮形成了簇集体。
短句来源
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  “激基缔合物荧光”译为未确定词的双语例句
    The critical concentration C_s of the transition from dilute to semi-dilute regime was found to be 0. 26g/dL, which has been interpreted as the concentration of dynamical contact of the polymer coils in the solution.
    观察了聚合物1由稀到浓的氯仿溶液的激基缔合物荧光强度与单生色团荧光强度比值的变化,得到溶液中高分子线团的动态接触浓度C_s=0.26g/dL;
短句来源
    It is possible to use the intermolecular excimer of SMP as a probe to study the molecular morphological changes of SMP.
    探讨用SMP分子间激基缔合物荧光作为研究SMP分子形态变化探针的可能性.
短句来源
    It was shown that the changes in the fine structures (I3/I1) of its fluorescence spectrum and/or its excimer formation efficiency (IE/IM) was well related to the gelation process and the gel swelling degrees.
    结果表明,Py荧光光谱精细结构的变化(以I_3/I_1为参量)或Py激基缔合物荧光强度与单体荧光强度之比(I_E/I_M)的变化与CS水凝胶的形成及溶胀程度有很好的对应关系.
短句来源
    THE FLUORESCENT EFFECT OF RING-SHAPED POLYSTYRENE EXCIMER IN DILUTE SOLUTION
    稀溶液中环型聚苯乙烯的激基缔合物荧光效应
短句来源
    Excimer formation of sulfonated polystyrene in solutions
    磺化聚苯乙烯溶液的激基缔合物荧光光谱研究
短句来源
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  excimer fluorescence
In addition to these emissions, the excimer fluorescence is often observed depending on the molecular structure of the siloxanes.
      
The experimental results were explained in terms of solute radical ion recombination leading to the Py monomer and excimer fluorescence.
      
We report new measurements of the near infrared (NIR) Xe2* excimer fluorescence in an electron-beam-excited Ar (90%)-Xe (10 %) mixture at room temperature.
      
Previous measurements up to a density N≈2×1026?m-3 discovered a broad excimer fluorescence band at ≈7800?cm-1, whose center is red-shifted by increasing N [A.F.
      
Fluorescence spectroscopic studies have shown that the BPDE molecules bound to DNA can interact in their photo-excited state giving strong excimer fluorescence when bound to poly(dGdC) · poly(dGdC).
      
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A butadiene-styrene copolymer of low styrene content (5%, Wt.) has been characterized by 1H NMR to have only isolated styrene units on the chain. The fluorescence spectra of the sample in dilute solutions of a good solvent (dichloroethane) at 25-26℃ showed monomer fluorescence only. Changes of the. fluorescence spectra from a good solvent to poor solvents (dichloroethane-methanol mixture), and from dilute to concentrated solutions up to the solid film confirmed that excimer formation exists between nonadjacent...

A butadiene-styrene copolymer of low styrene content (5%, Wt.) has been characterized by 1H NMR to have only isolated styrene units on the chain. The fluorescence spectra of the sample in dilute solutions of a good solvent (dichloroethane) at 25-26℃ showed monomer fluorescence only. Changes of the. fluorescence spectra from a good solvent to poor solvents (dichloroethane-methanol mixture), and from dilute to concentrated solutions up to the solid film confirmed that excimer formation exists between nonadjacent chromophores in the chain and between interchain chromophores. Com-parision of the spectra obtained from a dilute 8-solution and solid film gave us an estimation of the relative importance of the intrachain excimer interaction and interchain excimer interaction in the solid sample studied. These results may help us to visualize the interpenetration and entanglement of polymer coils during transition from a dilute solution to a concentrated one and to a solid polymer.

本文报导一种低苯乙烯含量(5%,Wt.)的丁二烯-苯乙烯共聚物,经~1H NMR证明其分子链上不存在相邻苯乙烯单元。荧光光谱结果表明,它在良溶剂(二氯乙烷)的稀溶液状态下只呈现单分子荧光。从良溶剂-θ溶剂(二氯乙烷-甲醇体系)及稀溶液-浓溶液-固体之荧光光谱的变化,证明形成了链内非近邻生色团之间和链间生色团之间的激基缔合物(Excimer)。从固体与θ溶剂的激基缔合物荧光的比较,还可区分链内非近邻和链间苯环形成激基缔合物对荧光强度的贡献。这一结果对阐明高分子链内非近邻和链间激基缔合作用提供了新的证据,并有助于了解高聚物本体中相互穿透、相互缠结的无规线团的形态。

A series of polymethylene-bis-β-naphthoates and bis-β-naphthyl alkanes and their derivatives have been synthesized and their fluorescence spectra have been studied.Intramolecular excimer formations have been observed in all cases. In the case of polymethylene-bis-β-naphthoates, the excimer fluorescence intensities are related to methylene chain lengths. The fluorescence intensity of the one with trimethylene chain is the strongest. In the case of substituted bis-β-naphthyl alkanes, by introducing electron-attracting...

A series of polymethylene-bis-β-naphthoates and bis-β-naphthyl alkanes and their derivatives have been synthesized and their fluorescence spectra have been studied.Intramolecular excimer formations have been observed in all cases. In the case of polymethylene-bis-β-naphthoates, the excimer fluorescence intensities are related to methylene chain lengths. The fluorescence intensity of the one with trimethylene chain is the strongest. In the case of substituted bis-β-naphthyl alkanes, by introducing electron-attracting groups in the side chain, the electron densities of the two naphthalene rings become unequal. The λ_(max) values of the fluorescence emissions of the intramolecular excimers are blue shifted in comparison with the unsubstituted 1, 3-bis-β-naphthyl propane. The λ_(max) values of the excimers remain unaltered, but the I_E/I_2 values decrease with the increase of solvent polarity. So that, their properties shown do not completely resemble that of the typical excimers nor that of the typical exciplexes.

本文报道几种双—β—萘甲酸多次甲基二醇酯及双—β—萘基烷烃次甲基链上被极性基团取代的衍生物的合成及其荧光谱。结果表明,它们都能形成分子内激基缔合物,对于双—β—萘甲酸多次甲基二醇酯来说,其分子内激基缔合物的荧光强度与链长有关,以三次甲基链为最大。对于双—β—萘基烷烃取代衍生物来说,由于吸电子基团的引入使两个萘环的电子云密度不等,它们所形成的分子内激基缔合物的荧光峰都比未取代的1,3—双—β—萘基丙烷有所蓝移。在极性溶剂乙腈中其分子内激基缔合物的荧光峰的位置虽然不变,但I_E/I_2值则有所降低,表现出既不完全与激基缔合物相同,又不完全与激基复合物相同的性质。

Poly (polytetramethylene ether glycol naphthalene 2, 6-dicarboxylate) (1) and poly (polytetramethylene ether glycol terephthalate) (2) have been synthesized and their fluorescence spectra are studied to show the existonce of excimer interaction between intrachain and interchain chromophores. For the solution of the polymer 1 in a good solvent, chloroform, the transition from dilute to semi-dilute and to concentrated regimes have been located by the change of ratio of the intensities of excimer fluorescence to...

Poly (polytetramethylene ether glycol naphthalene 2, 6-dicarboxylate) (1) and poly (polytetramethylene ether glycol terephthalate) (2) have been synthesized and their fluorescence spectra are studied to show the existonce of excimer interaction between intrachain and interchain chromophores. For the solution of the polymer 1 in a good solvent, chloroform, the transition from dilute to semi-dilute and to concentrated regimes have been located by the change of ratio of the intensities of excimer fluorescence to monomer fluorescence with concentration. The critical concentration C_s of the transition from dilute to semi-dilute regime was found to be 0. 26g/dL, which has been interpreted as the concentration of dynamical contact of the polymer coils in the solution. The transition concentration C~+ from semi-dilute to concentrated regime was found to be 7g/dL. In the solid film of 1, experimental evidence for the direct excitation of the excimer fluorescence from ground state excimer sites has been obtained.

合成了聚[2,6-萘二甲酸(聚四亚甲基醚二醇)酯](1)和聚[对苯二甲酸(聚四亚甲基醚二醇)酯](2);研究了它们在溶液和本体中的荧光光谱;论证了链间和链内非相邻生色团间有激基缔合作用存在。观察了聚合物1由稀到浓的氯仿溶液的激基缔合物荧光强度与单生色团荧光强度比值的变化,得到溶液中高分子线团的动态接触浓度C_s=0.26g/dL;亚浓区到浓区的转变浓度C~+=7g/dL。在聚合物1的本体中得到基态芳环层叠缔合物直接激发到激基缔合物的实验证据。

 
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