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电子转移     
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  electron transfer
     Energy Transfer from Ce~(3+) to Eu~(2+) and Electron Transfer from Ce~(3+) to Eu~(3+) in BaY_2F_8∶Ce, Eu Systems
     BaY_2F_8∶Ce,Eu中Ce~(3+)→Eu~(2+)的能量传递和Ce~(3+)→Eu~(3+)的电子转移
短句来源
     Kinetic Investigation of Electron Transfer Reaction between trans - [(en)_2(NO_2)Co(O_2CC_5H_5N)]~(2+)/Fe(Ⅱ)
     trans-[(en)_2(NO_2)Co(O_2CC_5H_5N)]~(2+)/Fe(Ⅱ)间电子转移反应动力学及机理研究
短句来源
     Ab intio Studies on the Electron Transfer O_2 + O_2~(·-)→O_2~- + O_2
     电子转移反应O_2+O_2~(·-)→O_2~(·-)+O_2的从头算研究
短句来源
     Theoretical Study of Self- Exchange Electron Transfer Reactions for Co(H_2O)_6~(2+/3+) System
     Co(H_2O)_6~(2+/3+)体系电子转移反应动力学的理论研究
短句来源
     Laser Flash Photolysis Studied on Photoinduced Electron Transfer from N,N,N′,N′-Tetra-(p-methylphenyl)-4,4′-diamino-1,1′-diphenyl Selenide (TPDASe) to Fullerenes (C_(60)/C_(70))
     富勒烯(C_(60)/C_(70))与N,N,N′,N′-四-(对甲苯基)-4,4′-二胺1,1′-二苯硒醚(TPDASe)间光诱导电子转移过程的激光光解研究
短句来源
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  electron-transfer
     THE EFFECT OF NONBRIDGING LIGANDS ON THE ELECTRON-TRANSFER REACTIONS OF COMPLEXES --The electron transfer reaction between Cis-[Co(en)_2Cl_2]~+ or cis-[Co(en)_2(OH_2)Cl]~(2+) and Iron(Ⅱ)
     非桥基配体对配合物的电子转移反应的影响——Cis-[Co(en)_2Cl_2]~+和Cis-[Co(en)_2(OH)_2Cl]~(2+)与Fe(Ⅱ)间电子转移反应
短句来源
     Outer-Sphere Electron-Transfer Stereoselectivity in the OXidation of[Co(en)_2ox] by ∧-[Co(edta)] ̄-
     ∧-[Co(edta)]-~氧化[Co(en)_2OX]外界电子转移反应的立体
短句来源
     Observation of Electron-Transfer Inverted Region in γ-MnO_2/K~3[Fe(CN)_6] Solution Interface
     γ-二氧化锰/K~3[Fe(CN)_6]溶液界面的电子转移反转区
短句来源
     The apparent heterogeneous electron transfer rate constant (ks) for the direct electron-transfer of SOFd was estimated to be (0.73±0.04) s-1.
     SOFd直接电子转移的表观速率常数ks为(0.73±0.04)s-1.
短句来源
     This article sums up the following principles from a series of experimental data:the apparent rate constant Kobsd of outer-sphere electron-transfer reactions between Cis-(Co(etaH)(en)_2) Br_3 and (Fe(CN)_6), formation constant of ion pair and electron transfer rate constant Ke each increase with an increase of pH of soluticn.
     用实验数据总结出下述规律:Cis-[Co(etaH)(en)_2]Br_3与[Fe(CN)_6]~(4-)间外界电子转移反应的表观速度常数kobsd、离子对形成常数kos和电子转移速度常数k_e均随pH值增大而增大。
短句来源
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  electronic transfer
     Structural modulation, electronic transfer and their correlation with the properties of Zn_(1-x)Co_xO nanorods
     Zn_(1-x)Co_xO纳米棒的结构调控,电子转移,和物理性能关联
     The number of electronic transfer Δ N=(x A- x B)/2( η A+ η B),which based on the concepts of absolute electronegativity, x , absolute hardness, η , and chemical potential, μ , in chemical reaction is first applied to the study of structure reactivity relationship of flotation reagents.
     首次以化学势 μ、绝对电负性x、绝对硬度 η概念为基础 ,推导出化学反应电子转移数ΔN =xA-xB2 (ηA+ ηB) ,应用于浮选捕收剂结构与性能关系的研究。
短句来源
     The electronic transfer coefficient (a), the number of electrons (n) and protons (m) involved in the electrode reaction of EBT and Ga(Ⅲ)-EBT were estimated to be 0.38 and 0.58 for a, 2 for n and m,resp ctively.
     测得EBT和Ga(Ⅲ)-EBT的电子传递系数(α)分别为0.38和0.58,电子转移数(n)和质子数(m)均为2°EBT在电极表面的饱和吸附量(Г_0~S)为5.6×10~(-10)mol/cm~2。
短句来源
     Thus, it is suggested that the electronic factor which means strong bonding of Ni to Ti3+ and electronic transfer between Ni and Ti3+ is not the main reason causing the strong metal support interaction (SMSI).
     这就表明,电子因素,即Ti~(3+)-Ni之间的强成键及电子转移似乎不是导致所谓的金属载体强相互作用(SMSI)的主要原因。
短句来源
     According to Mulliken overlap populations calculated for Ni -CO and C-O bond, it is found that the strong co-valent bonding of Ni to Ti3+ does not drastically suppress the ability of Ni atoms to adsorb CO, and the electronic transfer between Ti3+ and Ni atom does not lead to any increase in activation of adsorbed CO.
     计算的Ni-CO键和C—O键的Mulliken重叠集居指出,Ti~(3+)-Ni之间的强成键及电子转移没有导致Ni吸附CO的活性降低及吸附的CO的活化程度的提高。
短句来源
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  electron transition
     It is deduced that F~- and Cl~- form a bridged complex, [Cr~Ⅱ -X~- -Cr~Ⅱ ],~≠ in which electron transition is easily carried out.
     由此可推测,F~-、Cl~-在金属表面和铬酸的还原产物重铬酸铬形成了易发生电子转移反应的表面过渡态配合物〔Cr~Ⅰ-X-Cr~Ⅱ〕~≠.
短句来源
     The results indicated that: the electrochemical reaction of epinephrine shown semirreversible character of electron transition at platinum electrode in 0.5mol/L H 2SO 4 solution, the kinetic parameters such as diffusion coefficient, D R , is 2.75×10 -6 cm 2/s; heterogeneous electron transfer rate constant, k s, is 2.27×10 -4 cm/s.
     结果表明 :在 0 .5mol LH2 SO4 溶液中铂电极上 ,肾上腺素的电氧化反应具有准可逆电荷跃迁的特征 ,其动力学参数 ,扩散系数 (DR)为 2 .75× 10 - 6 cm2 s ,异相电子转移速率常数 (ks)为 2 .2 7× 10 - 4cm s.
短句来源
     A great deal of researches have indicated that organic compounds is promising nonlinear optical materials, since they can be synthesized with strongπelectron conjugated systems and electron transition between ligands and central atoms, which result in enhancement of nonlinear polarizability.
     大量的研究表明有机化合物是一种很有前途的非线性光学材料,可以合成结构中含有较强π电子共轭体系的化合物,配体与中心原子间的电子转移,大大提高了非线性极化率。
短句来源
     It is deduced that F- and Cl- have entered into on the surface of the cathod and formed a bridged complex with reduced chromium dichromate, [CrIII-X--CrIII], in which electron transition was easily carried out.
     由此可推测,F~-、Cl~-在金属表面和铬酸的还原产物重铬酸铬形成易发生电子转移反应的表面过渡态配合物,[Cr~Ⅲ-X-Cr~Ⅲ]~≠。
短句来源
     Their molecule structures have strong π electron conjugated systems and electron transition between organic ligands and center metal atoms, which result an enhancement of their nonlinear polarizabilities.
     它的结构中含有较强的π电子共轭体系,并且有机配体与中心原子间的电子转移,大大提高了其非线性极化率。
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  electron transfer
Photoinduced intramolecular electron transfer process from C60 moiety to carbazole moiety has been studied by nanosecond laser flash photolysis.
      
The electron transfer coefficient and apparent reaction rate constant were determined to be 0.861 and 1.27 s-1.
      
This causes a significant increase in the efficiency of further electron transfer to the primary quinone acceptor as compared to a system with two absolutely symmetric electron transfer branches.
      
Reactions of electron transfer from the primary to secondary quinone acceptors and from the multiheme cytochrome c subunit to photoactive bacteriochlorophyll dimer were used as probes of electron transport efficiency.
      
The thermoinduced transition of the acceptor complex to the conformational state facilitating electron transfer to the secondary quinone acceptor was studied.
      
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  electron-transfer
Although the two electron-transfer branches in the reaction centers (RC) of purple bacteria are virtually symmetric, it is well known that only one of them is functionally active (the A-branch).
      
The results indicate that residues Arg425 and Arg426 are involved in the formation of a heme-binding center and electrostatic interaction of cytochrome P450scc with its physiological electron-transfer partner, adrenodoxin.
      
The kinetics of oxidation of 4-hydroxybiphenyl (4-HBP) catalyzed by laccase from Polyporus pinsitus was studied in the presence of methyl syringate (MS), which acts as an electron-transfer mediator.
      
Application of the Quantum Beats Method to the Determination of the Electron-Transfer Radius in Nonpolar Solvents
      
Formation Enthalpy of Exciplexes with Partial Charge Transfer as a Function of the Electron-Transfer Driving Force
      
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  electronic transfer
The temperature dependence and rate of the Z1-center formation is in agreement with the corresponding results on FA-center formation, demonstrating that Z1-centers are formed as the consequence of an ionic process and not a mere electronic transfer.
      
This work indicates that the excitation to the first and second singlet induces an electronic transfer from the heteroatom in the case of ortho and para derivatives; for meta compounds, the same phenomenon occurs for the four first singlets.
      
Electronic transfer processes studied at different time scales by selective resonant core hole excitation of adsorbed molecules
      
Direct electronic transfer of PACS images reduces the number of steps involved in creating publication-quality images as well as providing the means to produce high-quality radiographic images in a digital environment.
      
Electronic transfer in spinel chalcogenides:119Sn M?ssbauer spectroscopy and7Li N.M.R.
      
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  electron transition
This line is due to an electron transition from the valence band to an inner atomic level (for example, the Kβ2 line for elements from Cu to Br).
      
The concentration dependence of the potential obeys the Nernst equation with a slope of 59.4 ±0.8 mV/pc corresponding to a one-electron transition VO2+ → VO2+ at pH 1.5-2.0 (cation function).
      
The electron transition of CHCl2CHO from the ground to lowest excited singlet state is accompanied by rotation of the CHC12 group, and the carbonyl fragment becomes nonplanar.
      
Among others, the lines of the negative carbon C2- ion and the lines corresponding to the electron transition in the neutral CO molecule are discovered.
      
A similar redistribution of intensity among electron transition bands has been observed when comparing the spectrum of an isolated C60 molecule and that of a C60 crystal.
      
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