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配体配合物
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  ligand complex
     Study on the Interaction of Mixed Ligand Complex Palladium(Ⅱ )-biquinoline-phenethylmalonate with DNA
     混合配体配合物钯(Ⅱ)-联喹啉-苯乙基丙二酸根与DNA作用研究
短句来源
     A mixed ligand complex of 1-phenyl-3-methyl-4-trifluoroacetyl-pyrazol-5-one(HPMTFP)and dimethyl sulfoxide(DMSO)with neodymium(Ⅲ)having molecularformula Nd(PMTFP)_3·(DMSO)_2 has been synthesized. Its crystal and molecular struc-ture has been determined by single crystal X-ray diffractometer.
     以1-苯基-3-甲基-4-三氟乙酰吡唑啉酮-5(HPMTFP)与二甲亚砜(DMSO)为配体,合成了Nd(PMTFP)_3·(DMSO)_2混合配体配合物.
短句来源
     3. The new Schiff base ligand (L_3) has been designed and synthesized, and we have obtained their three complexes 10~12. We have synthesized mono-Schiff base ligand complex 9 and a mix-coordinated complex 13. Crystal structures of complexes 9 and 13 have been determined by X-ray single analyses.
     3.设计合成了新的Schiff碱配体双呋喃甲醛缩1,2-丙二胺(L_3),得到了它们的3种配合物(10~12)以及1种单Schiff碱配体配合物9。 还得到了1种简单混配体配合物13。
短句来源
     Synthesis and Structure of a Mixed Ligand Complex of Tri(1-phenyl-3-methyl-4-trifluoroacetyl-pyrazol-5-one)bis(di-methyl sulfoxide)Neodymium
     三(1-苯基-3-甲基-4-三氟乙酰-5-吡唑啉酮)二(二甲亚砜)合钕混合配体配合物的合成及晶体结构的研究
短句来源
     Crystal Structure Characteristics of Isomer of Mixed Ligand Complex Cd(Ⅱ)-phenanthroline-malonate
     混合配体配合物镉(Ⅱ)-邻菲罗啉-丙二酸根异构体的结构特征研究
短句来源
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  ligand complexes
     Nine new mixed ligand complexes of the type Cr (β-dik ) C12L2, where L = y-picoline, β-dik = acetylacetone(acac), benzoylacetone (bzac), trifluoroacetylacetone ( tfac ) , thenoyltrifluroacetone(tta), 1, 1, 1, 2. 2, 3,3-heptafluoro-7, 7-dimethyl-4, 6-octanedione(fod);
     首次合成了九种[Cr(β-dik)Cl_2L_2]型混合配体配合物。 其中五种是:L为γ-甲基吡啶,β-dik分别为乙酰丙酮、苯甲酰丙酮、三氟乙酰丙酮、2-噻吩甲酰三氟丙酮、1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮;
短句来源
     The mixed ligand complexes of [Ni(dmit)(dmise)] n - ( n =2,1,0) were synthesized. The charge transfer salt of [BEDT TTF][Ni(dmit)(dmise)] was prepared by electrocrystallization. The products were characterized by EA, IR and ESR.
     合成了 [Ni( dmit) ( dmise) ]n-( n=2 ,1 ,0 )型混合配体配合物 ,用电结晶法制得 [BEDT-TTF]-[Ni( dmit) ( dmise) ]电荷转移盐 ,并用 EA、IR、ESR对目标产物进行了表征 .
短句来源
     SYNTHESIS AND CHARACTERIZATION OF CHROMIUM(III) MIXED LIGAND COMPLEXES CONTAINING β-DIKETONE
     铬(Ⅲ)含β一二酮混合配体配合物的合成和表征
短句来源
     SYNTHESIS AND CHARACTERIZATION OF CHROMIUM (Ⅲ) MIXED LIGAND COMPLEXES CONTAINING β-DIKETONE ( Ⅱ )
     铬(Ⅲ)含β-二酮混合配体配合物的合成和表征(Ⅱ)
短句来源
     A series of new type mixed ligand complexes were synthesized. The general for-mula was C_(52)H_(108)L4 N_9O_6S_4, Ln=Eu, Dy, Er,Yb,Y. The IR spectra of the complexes werestudied.
     合成了一系列新型稀土季铵盐混合配体配合物,元素分析结果证明其分子式的通式为:C_(52)H_(108)LnN_9O_6S_1(Ln=Eu,Dy,Er.Yb,Y).研究了该系列配合物的中红外光谱;
短句来源
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  “配体配合物”译为未确定词的双语例句
     Studied on Synthesis and Crystal Structure of Mixed-ligand Complex [Cd_2(phen)_4(bmal)_2]·3H_2O
     混合配体配合物[Cd_2(phen)_4(bmal)_2]·3H_2O的合成与晶体结构研究
短句来源
     Crystal Structure, Stacking Effect and 2D Network Assembled by Hydrogen Bonds of Quaternary Complex [Ce(CH_2ClCOO)_2(NO_3)(phen)(H_2O)]_2
     镧系四元混合配体配合物[Ce(CH_2ClCOO)_2(NO_3)(phen)(H_2O)]_2的晶体结构、芳环堆积效应和2D氢键网络
短句来源
     STUDIES ON COMPLEXES OF Co(Ⅱ),Ni(Ⅱ) IONS WITH ‘O_4N_2’ MACROCYCLIC LIGAND——Ⅱ. SYNTHESES AND CHARACTERIZATIONS OF COMPLEXES OF Ni(NCS)_2 ,Ni(NO_3)_2 WITH 1,7,10,16-TETRAOXA-4,13-DIAZACYCLOOCTADECANE AND STRUCTURE OF COMPLEX Ni(NCS)_2C_(12)H_
     Co(Ⅱ)、Ni(Ⅱ)与二氮杂18-冠-6配合物的研究——Ⅱ.Ni(NCS)_2、Ni(NO_3)_2与1,7,10,16-四氧杂-4,13-二氮杂环十八烷配合物的合成和Ni(NCS)_2与该配体配合物的结构
短句来源
     Crystal Structure and Spectrosopic Study of a Mixed Five-coordinationed Tetragonal Pyramid Cmplex:[Cu(phen)(ox)(H_2O)]·H_2O
     混合配体配合物[Cu(phen)(ox)(H_2O]·H2_O 合成和晶体结构
短句来源
     Studies on the Complexes of Rare Earth with Organic Ligands Containing Sulphur Atoms Ⅰ. Synthesis, Characterization and Structure for Complexes of Rare Earth with Diethyldithiocarbamate Et_2NH_2 [RE(S_2CNEt_2)_4]
     稀土与含硫有机配体配合物的研究 I.二乙氨基荒酸稀士配合物Et_2NH_2[RE(S_2CNEt_2)_4]的合成、表征与结构
短句来源
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  ligand complex
Extraction-photometric determination of molybdenum as a mixed-ligand complex with 2-hydroxy-5-chlorothiophenol and diphenylguani
      
It was found that a mixed-ligand complex was formed in 2-4 M HC1.
      
The molar absorptivity of the mixed-ligand complex was found to be 2.5 x 104 (595 nm).
      
The formation of a mixed-ligand complex of the composition Mo(V) : HCTP : DPG =1: 2 : 2 was shown.
      
Sorption-Spectrophotometric and Test Determination of Zinc(II) as the Mixed-Ligand Complex of 1,10-Phenanthroline and Bromopheno
      
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  ligand complexes
The problem of numerical modeling consisted in the construction of a system for the prediction of a change in the Gibbs free energy (Δ G) in the course of the formation of protein-protein and protein-ligand complexes.
      
The optimum conditions of the reaction and the composition of mixed-ligand complexes that are formed at the surface were found, and a scheme was proposed for the interaction at the interface.
      
Procedures were developed for the spectrophotometric determination of niobium and tantalum present simultaneously as mixed-ligand complexes.
      
It was found that different-ligand complexes formed in the presence of hydrophobic amines.
      
The effect of reagent concentration, time, and temperature on the formation of different-ligand complexes was studied, and their stoichiometry was determined by different methods.
      
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The cathodic processes of eletrodeposition of silver in AgNO_3-NH_3-pyridinecarboxylic

在电位法、纸上电泳法研究硝酸银-氨-吡啶甲酸体系配合物组成的基础上,采用线性电位扫描、时间电位法、旋转圆盘电极和示踪原子等方法研究了该体系的阴极过程和吡啶甲酸的作用.结果表明,当溶液中硝酸银含量为5×10~(-3)M,pH=9.2,银(Ⅰ)、氨和吡啶甲酸的摩尔比为1:2.5:5左右时,α-吡啶甲酸体系在一定过电位区,存在混合配体配合物的均相前置转化速率控制步骤,而β(或γ)-吡啶甲酸体系则在相同条件下不存在前置转化速率控制步骤.示踪原子法的研究结果表明,三种吡啶甲酸均在银电极上有不同程度的吸附.在此基础上,分别探讨了电极反应的历程以及吡啶甲酸对电极过程的影响.

Five new mixed ligand complexes of the type Cr(β-dik)Cl2py2,where β-dik = acetylacetone(acac) ,benzoylaceione(bzac), trifluoroacetylacetone(tfac) , thenoyltrifluroacetone (tta) , dibenzoyl-methane (dbm), py = pyridine , have been prepared. The electronic spectra from 300nm to 900nm were recorded and assignments of 4A2g 4T2g, were made. The ligand field parameter Dq value was calculated and compared with the values obtained by the rule of average environment Their IR spectra were measured from 400cm-1 to

首次合了五种Cr(β-dik)Cl_2py_2型(其中β-dik分别为乙酰丙酮、苯甲酰丙酮、三氟乙酰丙酮、2—噻吩甲酰三氟丙酮、二苯甲酰甲烷)和一种Cr(pmbp)Cl_2(thf)混合配体配合物、一种Cr(pmbp)_3配合物。并对上述化合物进行了电子光谱、红外光谱等的表征工作。

Nine new mixed ligand complexes of the type Cr (β-dik ) C12L2, where L = y-picoline, β-dik = acetylacetone(acac), benzoylacetone (bzac), trifluoroacetylacetone ( tfac ) , thenoyltrifluroacetone(tta), 1, 1, 1, 2. 2, 3,3-heptafluoro-7, 7-dimethyl-4, 6-octanedione(fod); L = N, N-dimethyl-formamide and N , N-dimethylacetamide, β-dik=bzac, tta, have been prepared. The electronic spectra from 300nm to 900nm were recorded and

首次合成了九种[Cr(β-dik)Cl_2L_2]型混合配体配合物。其中五种是:L为γ-甲基吡啶,β-dik分别为乙酰丙酮、苯甲酰丙酮、三氟乙酰丙酮、2-噻吩甲酰三氟丙酮、1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮;四种是:L分别为N,N-二甲基甲酰胺,N,N-二甲基乙酰胺,β-dik分别为苯甲酰丙酮和2-噻吩甲酰三氟丙酮。并对上述配合物进行了电子光谱、红外光谱的表征工作。

 
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