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芳基碘盐
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  aryl iodate
    This paper summaries the recent development of the hypervalent organoiodine compounds, and the application in the synthsis of complicated compounds, as transfer reagent (e.g. alkyl, alkenyl, alkynyl)and Aryl iodate.
    本文综述了有机高价碘化合物在合成中应用的进展,介绍了有机高价碘化合物的制备,阐述了有机高价碘化合物作为芳基,烷基,烯基,炔基,转移剂及芳基碘盐应用于复杂化合物的合成。
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  aryl iodate
    This paper summaries the recent development of the hypervalent organoiodine compounds, and the application in the synthsis of complicated compounds, as transfer reagent (e.g. alkyl, alkenyl, alkynyl)and Aryl iodate.
    本文综述了有机高价碘化合物在合成中应用的进展,介绍了有机高价碘化合物的制备,阐述了有机高价碘化合物作为芳基,烷基,烯基,炔基,转移剂及芳基碘盐应用于复杂化合物的合成。
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  “芳基碘盐”译为未确定词的双语例句
    CHEMISTRY OF MARINE RESOURCES V .THE ADSORPTION OF DIARYLIODONIUM AND POLYSTEROLIODONIUM TO THE MICRO-IODIDEION IN SEA WATER
    海洋资源的化学 Ⅴ.芳基碘盐及聚苯乙烯型碘盐对海水中碘离子的吸着性能研究
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Two different kinds of eledron donating ammes AH- Ⅰ and AH- Ⅱ in combination with electron accepting diaryliodonium salts were used as a new type of photoinitiation system for radical polymerization sensitive to visible light.The AH-- Ⅰ ammes, such as aliphatic and aromatic ammes, can only absorb light below 300--400 urn by themselves, but readily interact with iodonium salts to form a charge transfer complex (CTC), which extends the absorption largely into the visible range. The AH--Ⅱ amines, such as N--substituted...

Two different kinds of eledron donating ammes AH- Ⅰ and AH- Ⅱ in combination with electron accepting diaryliodonium salts were used as a new type of photoinitiation system for radical polymerization sensitive to visible light.The AH-- Ⅰ ammes, such as aliphatic and aromatic ammes, can only absorb light below 300--400 urn by themselves, but readily interact with iodonium salts to form a charge transfer complex (CTC), which extends the absorption largely into the visible range. The AH--Ⅱ amines, such as N--substituted derivatives of chalcone, coumarin ketone and styryl ketone, et al have a long conjugated structure and exhibit large absorbability in the visible range. These systems are stable in the bark. but rapidly undergo electron transfer reaction upon irradiation with visible light to generate initiating radicals. Both AH--Ⅰ/DPIO and AH-- Ⅱ /DPIO systems can efficiently induce photopolymerization of acrylates, acrylonitrile and styrene, etc. The photopolymerization rates and related kinetic equations for several systems were studied.

应用于可见光聚合的新型光敏化引发体系,是由二类不同的具有给电子作用的胺AH-Ⅰ、AH-Ⅱ和受电子作用的二芳基碘盐(DPIO)复合组成。AH-Ⅰ类胺,如脂肪族胶和芳香族胺的光吸收在300—400no以下,很容易和碘盐作用形成电荷转移络合物(CTC),使光吸收显著移至可见光区。AH-Ⅱ类胺如N~取代的查耳酮、吗啉酮和芪酮等衍生物,具有很大的共轭结构,并且在可见光区有很高的吸收能力,这些体系在暗处很稳定,然而在可见光作用下,很快发生电子转移反应,生成具有引发活性的自由基。AH-Ⅰ/DPIO和AH-Ⅱ/DPIO体系皆能有效地引发丙烯酸酯、丙烯腈和苯乙烯等光聚合。研究了几种体系的光聚合反应速度和相关的动力学方程。

This paper summaries the recent development of the hypervalent organoiodine compounds, and the application in the synthsis of complicated compounds, as transfer reagent (e.g. alkyl, alkenyl, alkynyl)and Aryl iodate.

本文综述了有机高价碘化合物在合成中应用的进展,介绍了有机高价碘化合物的制备,阐述了有机高价碘化合物作为芳基,烷基,烯基,炔基,转移剂及芳基碘盐应用于复杂化合物的合成。

In the presence of solid liquid phase transfer catalyst, the reaction of isopropylidene 5 tosyloxymalonate with electrophilic alkenes and diaryl iodoniums gives sulphones via the intermediate [ p CH 3C 6H 4SO 2 ].

报道了在固—液相转移催化(K2CO3/TEBA)条件下,5-对甲苯磺酰氧基丙二酸亚异丙酯与某些亲电烯烃、二芳基碘盐的反应,该化合物通过产生[p-CH3C6H4SO2㈠]而与亲电试剂反应生成砜.

 
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