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网络结构
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  networks structure
    CHARACTERIZATION OF NETWORKS STRUCTURE AND MECHANICAL PROPERTIES OF RADIATION CROSSLINKED CIS-1,4-POLYBUTADIENE
    辐射交联顺-1,4-聚丁二烯的网络结构特性和力学性能
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    STRUCTURE AND PROPERTIES OF EPOXY ACRYLATE-STYRENE SYSTEM POLYMER NETWORKS
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    STUDY ON THE RELATIONSHIPS BETWEEN THE STRUCTURE OF NETWORKS FOR PHASE STATE AND THE MECHANICAL PROPERTIES OF TPUE Ⅰ. THE MOLECULAR THEORY OF ELASTICITY FOR TPUE AT LARGE DEFORMATION
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    STUDY ON THE RELATIONSHIPS BETWEEN THE STRUCTURE OF NETWORKS FOR PHASE STATE AND THE MECHANICAL PROPERTIES OF TPUE Ⅱ.A COMPARISON BETWEEN THE MOLECULAR THEORY OF ELASTICITY FOR TPUE AND EXPERIMENTS
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  networks structure
Optimization of the metrological networks structure
      
Bayesian Networks structure learning can be used for this selection.
      
Global aspect of the Neural Networks structure We tempted to use Matlab predefined functions1 to conceptualize such a discriminator.
      
  inorganic networks
The chemical interactions between the organic polymer chains and the inorganic networks produced in-situ led to better properties of modified elastomer.
      
It was found that the inorganic networks chemically bound to polymaleimides enhanced the thermal stability of these nanocomposites greatly.
      
A new class of organic-inorganic materials can be prepared, based on inorganic networks and cycloor poly-(organophosphazenes).
      
The sol-gel technology is highly efficient for improving mechanical and thermal properties of polydiene elastomers by creating in them additional inorganic networks composed mainly of silica or silicates.
      
The incorporation of modifying Zn ions into "polydiene latex-silica" systems increases considerably their mechanical characteristics due to an increase of the interaction between the organic and inorganic networks.
      
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The complex reaction kinetics of the oxidation of naphthlene on a vanadium catatyst has been studied and the following three subjects of the research program have been fulfilled: (1)The establishment of a reaction network. (2)The discrimination of 12 kinetic models derived on the basis of the established network to obtain a reasonable, simple and reliable model. (3)Optimization of the parameters for the selected kinetic model by using Powell's method. Furthermore, a method for the treatment of complex reaction...

The complex reaction kinetics of the oxidation of naphthlene on a vanadium catatyst has been studied and the following three subjects of the research program have been fulfilled: (1)The establishment of a reaction network. (2)The discrimination of 12 kinetic models derived on the basis of the established network to obtain a reasonable, simple and reliable model. (3)Optimization of the parameters for the selected kinetic model by using Powell's method. Furthermore, a method for the treatment of complex reaction kinetics has been proposed in the present work. According to the characteristics of the reaction system and the particular of the experimental setup,data was treated in a sequential manner so that not only the complexity of data treatment can be much simplified but also the kinetics of both the main reaction and the side reactions can be obtained simultaneously.This method requires relatively less amount of experimental work but gives kinetic model satisfactorily for describing the experimental results.

本文报道了萘氧化复杂反应的动力学研究结果。完成了以下三方面的工作:1)明确了复杂反应的网络结构;2)在明确反应网络的基础上,探讨了十二种模型,按照一定的准则筛选出一个既合理又简单可靠的动力学模型;3)采用Powell优化方法确定了动力学模型中的各个参数。本文还探讨了处理复杂反应动力学的方法。根据反应系统的特殊性,以及实验装置的特点,采取分部处理的方法,简化了问题的复杂性,能在实验量不大的情况下同时研究萘氧化主反应和副反应的动力学,并得到了能够满意地描述结果的动力学模型。

The Fourier transform infrared spectra of Ho_2(C_2O_4)_3·3H_2O have been investigated in the range 4000—100cm~(-1). The Holmium oxalate hydrate crystal is an infinite network. In the normal coordinate treatment, two models Ⅰ and Ⅱ which may reveal the most important characteristics of the crystal are proposed. The assignment of the frequencies of the Ho_2(C_2O_4)_3·3H_2O has been made on the basis of complete normal coordinate analysis with the two models respectively using our NORVIB program. The average deviation...

The Fourier transform infrared spectra of Ho_2(C_2O_4)_3·3H_2O have been investigated in the range 4000—100cm~(-1). The Holmium oxalate hydrate crystal is an infinite network. In the normal coordinate treatment, two models Ⅰ and Ⅱ which may reveal the most important characteristics of the crystal are proposed. The assignment of the frequencies of the Ho_2(C_2O_4)_3·3H_2O has been made on the basis of complete normal coordinate analysis with the two models respectively using our NORVIB program. The average deviation between the calculated and experimental values is about 4.27cm~(-1).

研究了草酸钬水合物HO_2(C_2O_4)_3·3H_2O的100—4000cm~(-1)波数范围的付立叶变换红外光谱。由于草酸钬晶体具有无限网络的结构,为了简化计算过程,根据这一分子的结构特点,选择了两个能反映这一特征的模型Ⅰ和Ⅱ,分别应用NORVIB程序进行简正坐标计算处理,由位能分布的计算结果对这一波段的红外谱带做了指认,计算值与实验值的平均偏差为4.27cm~(-1)。

The effect of CPE chain structure on the modification of PVC blend has been studied by infrared spcciroscopy (IR), and differential scanning calorimetry (DSC). Dynamic mechanical spectra of the PVC/CPE blends indicate that they are partially compatable two phase systems. The morphology of the PVC/CPE blends were observed by transmission electron microscopy (TEM). High-impact strength of the PVC/CPE alloy is obtained when the rather regular network structure of CPE is formed.

本文用红外光谱法,差示扫描量热法(DSC)研究了氯化聚乙烯(CPE)的链结构性能及其对聚氯乙烯(PVC)改性的影响·用动态力学分析法(DMA)研究了PVC/CPE共混物的动态力学行为,表明CPE,PVC为部分相容两相体系。同时,用透射电子显微镜(TEM)观察了CPE在PVC/CPE共混物中的分布形态。当CPE在PVC/CPE共混物中形成比较完善的网络结构时,共混物具有更好的冲击性能。

 
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