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Extension of the polymethine chain of these compounds causes in the fluorescence spectra, in contrast to the absorption spectra, an increase in vinylene shifts, a decrease in deviations, and band narrowing.
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The influence of the flow cell volume on sensitivity and on band broadening have also been studied and a "chemical band narrowing effect" has been observed.
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Due to the interface design used and the chemical band narrowing effects of chemiluminescence, an apparent increase in efficiency is observed.
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Although the total band width coincides with the one in the bulk, the effective band narrowing at the surface leads to stronger correlation features in the quasi-particle spectra.
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The phenomena are interpreted by simultaneous effects of Pt surface dilution, enhanced electron back-donation from platinum to CO and Pt d-band narrowing.
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