Systemic analysis various factors which effect gel course, such as ratio of reactants and the dosage of catalyst, and probed into the better experiments conditions(the concentration of resorcinol and formaldehyde is more than 2% and the value of R/C is between 50 and 300);
The experiment results indicated that ultrasonic with unvarying temperature disposal shortened gel time and optimized quality of gels, and the factors of ultrasonic effect gel reaction velocity were analyzed;
The electron distribution of resorcinol and formaldehyde and single/multi-methyol resorcinol are calculated, then primary investigated the direction of transform from substabilization to stabilization and the principle of gel up-growth;
The metal doped resorcinol-formaldehyde gels are important target materials in inertial confinement fusion research,especially for application foreground of low-temperature freeze target research. In this paper ,resorcinol,formaldehyde and titanium nanoparticles are used as reactants, titanium nanoparticles are doped into RF gels successfully by physic method. In gelation process, the particle-diameter distributions are measured by zetasizer. The result indicates that the best dispersant for titanium nanopa...
Nano-composite energetic materials,hexahydro-1,3,5-trinitro-1,3,5-triazine/resorcinol-formaldehyde(RDX/RF) aerogel,was prepared by crystallization of RDX in the N,N-dimethyllformamide(DMF) within the nano-dimensional pores of resorcinol-formaldehyde(RF) gel matrix.The structures of RDX/RF aerogel were characterized by atomic force microscopy(AFM),scanning electron microscopy(SEM),X-ray powder diffraction(XRD),and BET method.Experimental results show that the grid size formed by RF ranges from several to sev...
Resorcinol-formaldehyde(RF) gel films were synthesized by a series of processes such as sol-gel,supercritical drying and carbonization using resorcinol and formaldehyde.The main factors that affect the properties of aerogels such as HAC content and the reaction temperature were investigated to indicate the mechanism of self-assemble RF films.The micro-morphology and structures of the gel films were characterized by FT-IR and SEM.It was found the thickness of RF aerogel films is about 50 μm,the size of parti...