In the presence of alkaline soap as emulsifier and catalyst, hydrogenated rosin sucrose esters (HRSE) were synthesized by transesterification reaction of hydrogenated rosin ethyl ester and sucrose under the conditions of (125±1)℃,molar ratio of hydrogenated rosin ethyl ester to sucrose 1 ∶1, pressure 0.090 MPa without solvent.
The paper introduced an industrial test(300 t/a) in which sucrose fatty acid esters(SE) were synthesized by transesterification of fatty acid ethyl esters with sucrose in propylene glycol solvent.
RESULT homogeneous transesterification between EPA DHA ethyl esters and glycerol bigan at 120℃,and equilibrated at a ratio of 45% inversion of EPA DHA into glycerides winthin 1 hr at 170℃.
The result indicated that the reacting mixture containing dioxane 11.3 mL /g HDCA which had been added ethyl chloroformate drop wise should be keep at 10 ℃ for 30 min,then,rising to 15 ℃ for another 20 min in the step of forming mixed anhydride,and 1.5 mol/L NaOH was used to dissolve taurine before aminolysis,and crude product was recrystalled by acetone in purifying process.
3,4-difluoroaniline react with carbon disulfide in existence of triethylamine, then react with ethyl chloroformate and get 3,4-difluorophenyl isothiocyanate.
Diethyl carbonate, ethanol, ethyl chloroformate, ethyl acetate,1,1-diethoxyethane were separated and qualitatively analyzed respectively, andexplained the formation of the by-products from the reaction mechanism.
The synthesis of Flupirtine maleate was studied. 3-nitro-2,6-diaminopiridine was chosen as start material,which was amined sperately at position 2 and 6, then catalystically hydrogenated and acylated with ethyl chloroformate, finally salted with maleic acid to get Flupirtine in a total yield 76.5%.
Several 1-(substituted phenoxy)-3-{[4-(4-trifluoromethyl) phenoxy] piperidin-1-yl} propan-2-ols (str.II) were prepared in a six-step reaction sequence starting from methylamine and ethyl acrylate and evaluated for antidepressant activity.
Synthesis of novel 3-[5-ethyl-2-(2-phenoxy-ethyl)-pyridin]-5-substituted isoxazoline libraries via 1,3-dipolar cycloaddition and evaluation of antimicrobial activities
Furancontaining bisoxazoline with 4-benzyl on oxazoline rings exhibited higher enatioselectivity than congeneric bisoxazolines with 4-ethyl on oxazoline rings.
Meanwhile, the fluorescence lifetime of 2-[2-(9-ethyl-9H-carbazol-2yl)-vinyl]-quinolin-8-ol and its zinc complex showed long lifetime in benzene solution.
The effect of pH value on the electrostatic layer-by-layer self-assembly and the photo-responsive behavior of Poly{2-[4-(4-ethoxyphenylazo)phenoxy]ethyl acrylate-co-acrylic acid} (PEAPE) was studied.
The catalytic constant (25 s-1) andKM (0.17 mM) for the immobilized enzyme for the hydrolysis of N-acetyl-L-tyrosine ethyl ester are comparable to the corresponding characteristics for the free enzyme.
The Michaelis constant of the elastase for N-t-Boc-L-alanine p-nitrophenyl ester is 0.10 mM; the Michaelis constant of the cathepsin G for N-benzoyl-L-tyrosine ethyl ester is 0.42 mM.
S-naproxen imprinted polymer was prepared with acrylamide as a functional monomer, 1,4-butanediyl diacrylate as a new kind of crossliner, and 2,4,6-trimethylbenzoylphenyl-phosphinic acid ethyl ester as photoinitiator.
The reaction of carboxymethyl polysaccharides and their ethyl esters with amines was studied with the aim to determine how the structure of the polymeric acylating agent affects the composition of the reaction products.
High-temperature copolymerization of ethyl esters of vinyl- or isopropenylcyclopropanecarboxylic acids with SO2 was studied as a route to functionally substituted unsaturated polysulfones.
4-Butyl-1,2-diphenylpyrazolidine-3,5-dione derivatives were prepared by its condensation with Schiff bases formed from p-aminobenzoic acid and its methyl and ethyl esters as amine components and substituted aromatic aldehydes.
1,3-Diaryl-4-isocyanatopyrazoles were obtained by reaction of 1,3-diarylpyrazole-4-carboxylic acids with ethyl chloroformate and sodium azide or by reaction of 1,3-diarylpyrazole-4-carbonyl chloride with trimethylsilyl azide.
Isomerization of 2-allyl-6-methylaniline by the action of potassium hydroxide at 300°C afforded cis and trans isomers of 2-methyl-6-(1-propenyl)aniline which were converted into the corresponding carbamates by treatment with ethyl chloroformate.
Amino acids have been chosen as model polar compounds of biological interest, and 9-fluorenylmethyl chloroformate (FMOC) and (+)-1-(9-fluorenyl)ethyl chloroformate (FLEC) have been used as derivatizating reagents.
benzoic, phenylacetic, phenylpropenoic (cinnamic), phenylglycolic (mandelic), phenylpropionic and their variously substituted forms can be converted almost instantly to derivatives amenable to GC by treatment with methyl or ethyl chloroformate.
The current methods for the preparation of ethyl orthosilicate do not give satisfactory results.It is found that the low yield is due to the use of excess alcohol,which,in presence of hydrogen chloride,produces water and causes the ethyl orthosilicate to undergo a hydrolytic polycondensation.The condensation products have been isolated and identified as 1,3-hexaethoxydisiloxane and 1,3,5- octaethoxytrisiloxane. An improved method,consisting of the addition of equivalent quantities of silicon tetrachloride a...
The overall reaction of chlorination of O,O-diethyldithiophosphoric acid,giving O,O-diethyl-thiophosphoryl chloride and sulphur monochloride,is found to consist of following successivesteps:One of the reaction intermediates,bis-(diethylthionophosphate) disulphide,has been isolatedand identified,and another intermediate,the diethyhhionophosphate sulphur chloride,whichis too unstable to be isolated,has been identified indirecdy through the following reaction:(?)A crystalline solid appearing in the course of t...