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      coordination compounds
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  配合物
     The results indicated that there were two coordination compounds, La(ClO_4)_3·18C6·3H_2O·2CH_3CN and La(ClO_4)_3·2(18C6)·3H_2O·2CH_3CN formed in this system at 25℃.
     结果表明,该体系在25℃时形成了两种化学计量的配合物,其组成分别为:La(ClO_4)_3·18C6·3H_2O·2CH_3CN和La(ClO_4)_3·2(18C6)·3H_2O·2CH_3CN。
短句来源
     Two coordination compounds have been isolated, the samples having the composition La(ClO_4)_3·18C6·3H_2O and La(ClO_4)_3·2(18C6)·3H_2O.
     制得了组成为:La(ClO_4)_3·18C6·3H_2O,La(ClO_4)_3·2(18C6)·3H_2O等的配合物
短句来源
     Thermodynamics on the Reaction of Formation of the Coordination Compounds Lu(C_5H_8NS_2)_3(C_(12)H_8N_2)
     三元配合物Lu[(C_5H_8NS_2)_3(C_(12)H_8N_2)]生成反应的热力学(英文)
短句来源
     The Influence of Medium on Stability of Coordination Compounds Ⅰ. The System Cu(SCN)~+-NaNO_3-C_2H_5OH-H_2O
     介质对配合物稳定性的影响 Ⅰ.Cu(SCN)~+-NaNO_3-C_2H_5OH-H_2O体系
短句来源
     Two Coordination Compounds Using Semicarbazide (SCZ) as Bidentate Ligands: [Ni(SCZ)_3](NO_3)_2 and Cu(SCZ)_2Cl_2
     氨基脲双齿配位配合物[Ni(SCZ)_3](NO_3)_2和Cu(SCZ)_2Cl_2的研究(英文)
短句来源
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  配位化合物
     STUDIES ON THERMAL STABILITIES OF COORDINATION COMPOUNDS BY GAS CHROMATOGRAPHY——Ⅸ.THERMAL DECOMPOSITION OF Fe_2(C_2O_4)_3—HZSM-5 AND Fe_2(C_2O_4)—HY
     气相色谱法研究配位化合物的热稳定性——Ⅸ.Fe_2(C_2O_4)_3—HZSM-5和Fe_2(C_2O_4)_3—HY的热分解
短句来源
     STUDIES ON THERMAL STABILITIES OF COORDINATION COMPOUNDS Ⅹ.Termal Decomposition of K_3[Fe(C_2O_4)_3]/HZSM-5 and K_3[Fe(C_2O_4)_3]/HY
     气相色谱法研究配位化合物的热稳定性——X.K_3[Fe(C_2O_4)_3]在HZSM-5和HY沸石上的热分解
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     A Synthetic Study of Co(Ⅱ) 、Cu(Ⅱ)、Fe(Ⅱ)、Zn(Ⅱ) with dithiomethyle coordination compounds
     Co(Ⅱ)、Cu(Ⅱ)、Fe(Ⅱ)、Zn(Ⅱ)与二乙氨基二硫代甲酸盐配位化合物的合成研究
短句来源
     NMR STUDIES OF THE COORDINATION COMPOUNDS OF 18 - C - 6 AND CoCl_2 IN ACETONE SOLUTION
     在丙酮溶液中18—冠—6与CoCl_2配位化合物的NMR研究
短句来源
     REFINE CALCULATION OF THE COORDINATION COMPOUNDS CH 2LiX
     配位化合物CH_2LiX的修正计算(英文)
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  “coordination compounds”译为未确定词的双语例句
     STUDIES ON THE SOLID STATE REACTIONS OF COORDINATION COMPOUNDS: LXIX STEPWISE REACTION OF CuCl_2.2H_2O WITH 2,2'-BIPYRIDYL
     STUDIES ON THE SOLID STATE REACTIONS OF COORDINATION COMPOUNDS: LXIX STEPWISE REACTION OF CuCl_2.2H_2O WITH 2,2'-BIPYRIDYL
短句来源
     Ruthenium Coordination Compounds with Polypyridines Ⅶ. Non-intercalative Binding of Ru(Ⅱ) Complexes with Calf Thymus DNA
     Ruthenium Coordination Compounds with Polypyridines Ⅶ. Non-intercalative Binding of Ru(Ⅱ) Complexes with Calf Thymus DNA
短句来源
     RUTHENTUM(Ⅱ)COORDINATION COMPOUNDS WITH POLYPYRIDINE (Ⅲ):STEREOSELECTIVITY OF TRIS(PHENANTHROLINE)UTHENIUM BINDING IN DNA
     RUTHENTUM(Ⅱ)COORDINATION COMPOUNDS WITH POLYPYRIDINE (Ⅲ): STEREOSELECTIVITY OF TRIS(PHENANTHROLINE)RUTHENIUM BINDING IN DNA
短句来源
     SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH_3)_4CO_3)Cl and (Co(en)_2CO_3)Cl WITH NH_4SCN
     固相配位化学反应研究ⅩⅩⅩⅩⅢ.[Co(NH_3)_4CO_3]Cl、[Co(en)_2CO_3]Cl与NH_4SCN的固相取代反应
短句来源
     Studies on Phase Equilibrium of LaCl ̄3 ·3H_2O-18C6-C_2H_5OH System at 25℃ and Synthesis and Characterization of Solid Coordination Compounds
     LaCl_3·3H_2O-18C6-C_2H_5OH体系(25℃)的相平衡研究及
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  coordination compounds
The sorption of platinum(II) and platinum(IV) at the surface of sorbents yields coordination compounds luminescing at 77 K under UV irradiation.
例句来源      
In the course of complexation in each of the uranyl(VI)-ligand systems studied, only coordination compounds UO2L2 (L- is the deprotonated form of the ligand) are formed.
例句来源      
Separation of Trivalent Americium and Rare-Earth Elements from Iron Impurity Using Certain Coordination Compounds
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The synergic effect was attributed to the formation of coordination compounds that are more hydrophobic than the initial compounds and have stronger bonds of Ce(III) with the ligands.
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Electrophysical Properties of Coordination Compounds Based on Cobalt(II) and Manganese(II) Chlorides and ε-Caprolactam
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         In this paper the thermal stabilities of 25 oxalato coordination compounds have been studies mainly by gas chromatography.Information which can not be obtained from TG or DTA has been obtained by this method.The principal findings may be summarized as follows: 1.When the thermal decomposition of the oxalato complexes of various metals was carried out in helium,the crystalization and the coordination water were expelled.Thermal decomposition in hydrogen gave additional water as a result of ...
            以气相色谱为主要手段,测定了25种草酸配位化合物的热稳定性,得到了许多差热分析和热失重方法所得不到的信息。二价金属草酸盐的热分解可分为三种类型:产生CO_2和金属,产生CO,CO_2和金属氧化物以及产生CO和金属碳酸盐。某些草酸盐的热分解同时按其中的两种类型进行。草酸配位化合物分解CO_2峰值温度随中心离子标准电极电位增加而降低,大致有线性关系t_p=-86.2E_1~0+273(℃)。还对二价金属草酸盐进行了理论计算,讨论了电子结构与热稳定性的关系。
文摘来源
         The hydrolytic polymerization of Cr3+ at rather high concentrations was studied pH-metrically. Four series of chromic nitrate solutions have been prepared of 0.160M, 0.200M,0.250M and 0.320M concentration, each with various pH and all with 0.5M sodium nitrate. The solutions were hold in polyethylene bottles and kept at 40±1°C. From time to time, a small portion of each solution was taken and its pH was measured at 30±0.1°C. When difference between the pH values measured over an interval of four days was les...
            本文用pH法研究了Cr~(3+)在较高浓度下的水解聚合状态,发现了同一种Cr~(3+)水解体系的第二种“根+节”配位化合物——Cr[Cr(OH)]_n~((3+2n)+)(n=1,2)。其水解平衡常数为lgβ_(1,2)=-2.68,lgβ_(2,3)=-3.84。
文摘来源
         Solvent extraction of metal ions may be regarded as a multicomponental coordinative chemical reaction between two immiscible phases. This thermodynamic process is evidently influenced by the spatial configuration of both ligand and metal ion to be extracted. The steric feature consisting of shielding, conformational and spatial effects are, however, determined by the composition, structure and configuration of the coordination compounds. Steric effects play an important role in the investigation...
            金属的溶剂萃取是两相间多组成的配位化学反应,配位体及被萃离子的空间结构对这个热力学过程有显著影响,它与形成热力学稳定的配位化合物有关。包括屏蔽效应,构象效应和空间张力在内的结构空间效应不仅决定于配位体及金属离子的结构,同时也与所形成的萃合物的结构和构型直接相联系,它是萃取剂分子设计数学模型中的重要结构参数。 稀土配位化合物一般为八面体构型,结构空间效应的影响不显著,但镧系收缩特性,为应用配位体的结构空间效应提供了可能性。 本文着重讨论了中性磷(膦)酸酯及酸性磷(膦)酸酯萃取稀土反应中的结构空间效应对萃取性能的不同影响,以及与反应的熵变值及萃合物结构的联系,同时对萃取稀土反应中有机取代基团Es值的测定作了探讨。
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