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      coordination complexes
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  配合物
     Synthesis, Structure and Photophysical Properties of Zn-Ln(Ⅲ) (Ln=Eu, Tb) Heterometallic Coordination Complexes
     Zn-Ln(Ⅲ)(Ln=Eu,Tb)杂核配合物的合成、结构及光物理性质
短句来源
     RESEARCH ON THE STRUCTURE AND REACTIVITY OF Mc_4Bzo_2[14] HEXAENATO(2-)N_4 METAL COMPLEXES Ⅱ. STUDY ON THE ELECTRONIC ABSORPTION SPECTRA OF ML AND MLX_x TYPE COORDINATION COMPLEXES
     Me_4Bzo_2[14]六烯(2-)N_4金属配合物的结构和反应性研究——Ⅱ.ML和MLX_x型配合物的电子吸收光谱研究
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     Two d-f heterometallic coordination complexes EuZn(C8H7O3)5(phen)(H2O)(1) and TbZn(C8H7O3)5(phen)(H2O)(2) were synthesized with hydrothermal reaction. These two complexes exhibit strong luminesecent emission.
     采用溶剂热方法合成了两种具有良好发光性能的d-f异核金属配合物EuZn(C8H7O3)5(phen)(H2O)(1)和TbZn(C8H7O3)5(phen)(H2O)(2).
短句来源
     Structure and Fluorescence Behavior of the Cellulose Ester/Eu(Ⅲ)/Carboxylic Acid Coordination Complexes
     纤维素醚/Eu(Ⅲ)/羧酸配合物的结构及荧光性能
短句来源
     In this paper,we synthesized the coordination complexes of water-soluble cellulose ethers/Eu(Ⅲ) with fluorescence emission,i. e. CMC/Eu(Ⅲ),MC/Eu(Ⅲ) and HEC/Eu(Ⅲ).
     合成了具有发光性能的水溶性纤维素醚/Eu(Ⅲ)的配合物,即羧甲基纤维素(CMC)/Eu(Ⅲ)、甲基纤维素(MC)/Eu(Ⅲ)和羟乙基纤维素(HEC)/Eu(Ⅲ),讨论了这些配合物的结构,并由FTIR加以证实。
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  配位化合物
     N, N-Diethyldithiocarbamate (dtc) as a ligand can combine with both molybdenum and the rare-earth elements to form dinuclear coordination complexes [Mo (dtc)4][Ln (dtc)4](Ln=La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er). Their redox properties and the electrochemical characteristics were studied.
     研究了N,N-二乙基二硫代甲酸根(dtc)作配体的双核配位化合物[Mo(dtc)4][Ln(dtc)4](Ln=La,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho和Er)的氧化还原性质及其在电极过程中的电化学特性.
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  “coordination complexes”译为未确定词的双语例句
     In this system there are two coordination complexes: Er(Met)(NO3)3H2O and Er(Met)4(NO3)3·6H2O.
     (NO_3)_3·6H_2O。
短句来源
     In the coordination complexes of the sample soil, whose concentration is 15mg/g, inhibitory effect on bacteria is 47%-63%, on mold is 23%-34%, and on soil-catalase is 9. 5%-38. 7%, dehydrogenase activity obviously decreases;
     在化合物浓度为15mg/g土样中:细菌生长的抑制率达47%-63%,霉菌为23%-34%,过氧化氢酶抑制率为9.5%-38.7%,脱氢酶活性明显降低。
短句来源
     Novel C 2-symmetric chiral bis(oxazoline) ligands 1a~1f were synthesized. Their coordination complexes with Ti(OPr-i) 4 were applied in the diethylzinc addition to aldehydes with good yields and medial ee values (55%).
     合成了 6个具有C2 对称性的类卟啉手性双唑啉配体 ,将这些化合物与Ti(OPr i) 4 配位应用于二乙基锌对芳香醛的不对称加成反应 ,获得了较高的化学产率和中等程度的ee值 ( 5 5 % ) .
短句来源
     The Effect of Coordination Complexes of Rare Earth Chlorides with Imidazole on Soil microenvironment.
     氯化稀土与咪唑配合物对土壤微环境的影响
短句来源
     THE SYNTHESIS OF NEW PLATINUM (Ⅱ) AND (Ⅳ) COORDINATION COMPLEXES CONTAINING MALONATE AND ITS DERIVATIVES
     新抗肿瘤铂络合物的合成
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  coordination complexes
H2O coordination complexes give higher energies, and hydroxylated silicon atoms on SiO2 are considered as primary water-adsorption centers.
例句来源      
It has been established that during dehydration there are abrupt changes in the geometrical dimensions of the particles, caused by breakdown of coordination complexes between surface silicon atoms and water molecules.
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The resulting polymeric coordination complexes with layered structures were characterized by X-ray diffraction analysis and IR spectra.
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The latter can act as ligands in the formation of coordination complexes of metals (Co, Cu, Zn, Cd).
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The behavior of olefins as ligands of the coordination complexes with silver ions in liquid chromatographic systems is analyzed.
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         A combination of transmission electron microscopy, X-ray diffraction, and infrared spectroscopy has been employed to study the nature of optical absorption of a transparent glass ceramic doped with Fe2O3.Glasses based on the Li2O-MgO-Al2O3-SiO2 system have the following wt% compositions: 65-75 SiO2, 2.8-4.8 Li2O, 18-24 Al2O3, 1.3-3.4 MgO.The factors which are chiefly responsible for the light absorption of the transparent glass-ceramic may be: the formation and growth of crystals, the formation of iron elec...
            文中综合采用透射电镜,X-射线衍射和红外光谱等来分析含铁透明微晶玻璃的光吸收本质。 玻璃基于Li_2O-MgO-Al_2O_3-SiO_2系统,其化学组成范围是SiO_265~75, Li_2O2.8~4.0,Al_2O_3 18~24,MgO1.3~3.4(重量百分率)。着重讨论了杂铁离子和晶化时间对本系统光吸收的影响。 导致微晶玻璃光吸收的主要因素有:晶体的形成和生长,铁离子场的构成及其配位多面体,Fe~(2+)(Fe~(3+))离子周围配位场的交替相互作用和场强,以及吸收中心的对称程度等。
文摘来源
         We have studied the mechanism of the polymerization of silicic acid in wide pH range. Experimental results showed that the cation of the added salts combined either with water forming aquo-metal ions or with the anion of silicic acid forming coordination complexes and thus giving rise to two different effects on the rate cf polymerization of silicic acid: electrostatic and chemical reaction.The relative degree of these two effects depends on the pH of the solution and the total cationic effect o...
            在广泛pH范围内研究了硅酸聚合中盐效应的机理。实验结果表明:外加盐的阳离子既可与水配位形成水合金属阳离子,又可与硅酸负离子形成配合物。因此外加盐的阳离子同时以静电效应和化学反应两种机理来影响硅酸的聚合速度,这种影响随溶液pH增大而加强。在强酸性溶液中,外加盐被酸化成的酸和硅酸或硅酸阳离子反应,以化学反应机理来改变硅酸的聚合速度。这一作用随溶液pH增大而减小。根据上述机理,提出了一个表示硅酸聚合速度与包括盐效应在内的各种因素的关系式,由此求得的计算值与实验值基本符合。
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         In the presence of cetyltrimethylammonium bromide (CTMAB) sue ascorbic acid (AA) and chloroacetic acid (CAA) as auxiliary complexing agents, in the range of PH 0.9 to 1.6 pyrocatechol violet (PV) with tin (Ⅳ) formed a colour-producing reaction system of multicomponent coordination complexes PV-Sn (Ⅳ) -AA-CAA-CTMAB, the sensitivity for PV as a spectrophotometric agent is highest (ε_(662)=1.43×10~5L. mol~(-1). cm~(-1)). The compsition of complexes for the main component parts is Sn (Ⅳ):PV:CT...
            在溴化十六烷基三甲基铵(CTMAB)存在下,以抗坏血酸(AA)和氯乙酸(CAA)为辅助配位体,在pH0.9~1.6范围内邻苯二酚紫同锡(PV)形成多元PV—Sn(IV)—AA—CTMAB配位显色体,使PV作为光度试剂达到迄今为止最高的摩尔吸光系数—ε_(662)=1.43×10~5L·mol~(-1)·cm~(-1)。锡浓度在范围服0.02~0.7ppm从比尔定律。方法可直接用于锌合金和铜合金中微量锡的测定。
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