Three new mononuclear manganese complexes MnL 2 1·PhCOO -, MnL 2 2·PhCOOH, MnL 2 2·HAc were synthesized, and were also characterized by elemental analysis, determination valence, molar conductivity and electronic magnetic susceptibility, thermoanalyses, IR,Uv Vis,ESR spectra etc Possible structures of these complexes were brought out HL 1 and H 2L 2 represented salicylidene 1,2 phenylenediamine and salicylidene ortho hydroxyphenylamine respectively, both of which were tridentate ligands
ESR spectrum with no superfine structure confirms the presence of V 4+ and the average valence of vanadium in the product is +4.30 on the basis of TG and XPS.
It was found that KNO_3/AC and Ba(NO_3)_2/AC were reduced at 400℃ and 350℃ respectively. Furthermore,the samples were not reduced completely,and formed higher valence(state)nitrogen compound N_2 and N_2O(for their reduction products).
This study aimed to describe the distribution of water-arsenic (As) valence states and its relationship to areas with endemic arsenism in the Datong basin.
This led us to conclude that the fraction of each water-arsenic valence state should be studied when determining the arsenic content of drinking water.
In the present investigation, the influence of various oxides such as Na_2O, CuO,CaO,BaO, B_2O_3,SnO_2 on the electro-conductivity of phospho-vanadate glass was described, and the values of activation energy of conduction for different glasses were reported.From the view-point of crystal chemistry, the relationships between the composition and the electro-conductivity were explained with the hypothetical structural model of the glass.The authors assumed that the theory with regard to the mechanism of conduc...
In the present communication a practical method for obtaining a semi-conducting glass with high electrical conductivity was described. The authors have attempted to utilize a mixture of BaO(25%), TiO_2(45%) and SiO_2(30%)as the fundamental composition for this investigation,and to the mixture the flux(Na_2SiF_6), various reducing agents(carbon powder, Al, Zn or Mg powder, tartaric acid) and oxides(Fe_2O_3, SnO_2, Sb_2O_3, V_2O_5) were then added. Each batch being melted separately under different atmosphere...
The formation of divacancies in MgO, their amount, the influence from dopant andthe influence on sintering were studied. There are many arrangements of the □Mg~(2+) and □o~(2-) in MgO. By some arrangementsdivacancy will not be formed.The probability is less than one. The concentration of diva-cancies formed at 1,800℃ is estimated as less than 10~(-5). When MgO is doped with Fe_2O_3, the concentration of divacancies is increased, andthere are two mechanisms of the formation of divacancies. The dopant Fe_2O_3...