Two complexes with structure of [3Fe2S] were obtained by the reaction of [Fe2S2(CO)6] and PMe2Ph. The average valence of each Fe atom is 4/3 and the bond lengths of Fe-Fe are about 2.60 A.
The adulteration of Cl" leads to the increase of the chemisorbed oxygen in the oxygen vacancies, the mobile lattice oxygen, Co + content, the average valence of Co ions and catalytic activity. While the adulteration of F" has opposite effects.
The average valence of Fe/Co in SrFe_(1.5 -x)Co_xO_(3.25+δ) systems was determined by iodometric titration. The structure of SrFe_(1.5 -x)Co_xO_(3.25+δ) was determined by X-ray powder diffraction.
ESR spectrum with no superfine structure confirms the presence of V 4+ and the average valence of vanadium in the product is +4.30 on the basis of TG and XPS.
The paper studied the reactions for the formation of subhalides with average valence being less than 2.5 by the reaction of titanium with its liquid tetrachloride at lower temperature 973K in KC1 melt.
X-ray absorption near-edge structure (XANES) analysis showed that the average valence of Cr in Sr3Cr2O8 is +5.2, suggesting the presence of mixed valence states in this compound.
detail by MO theory. The important role of the bridge sulfur for the formation of cluster and the effect of bridge sulfur on the Fe-Fe bonding have been noted. On the basis of theoretical analysis the expression of the Fe average valence for Fe-S cluster compounds has been proposed.
The paper studied the reactions for the formation of subhalides with average valence being less than 2.5 by the reaction of titanium with its liquid tetrachloride at lower temperature 973K in KC1 melt.An improved hydrogen evolution method has been developed to determine Ti2+ and Ti3+ .
A series of V-P-O catalysts in the range of P/V ratio = 0.9, 1.0, 1.1, with different calcination temperature and calcination atmosphere for n-butane oxidation to maleic anhydride were prepared by the method of benzyl alcohol reduction. Crystal phases of the catalysts were determined by XRD and FT-IR. The average valence of vanadium in the catalysts was determined by chemical titration. It was considered that the main factor which was related to seclectivity is the formation of crystalline catal...