In the case of ethylene glycol being used as chelating agent, the carbon contents of LiFePO4product were 3.3wt.% and 6.4wt.%, respectively, for ferric compound and ferrous compound, the corresponding discharge capacities were 145mAh/g and 75mAh/g at rate of 0.1C.
In the case of citric acid was used as chelating agent, the carbon contents of LiFePO4 product were 6.0wt.% and 10.1wt.%, respectively, for ferric compound and ferrous compound, the corresponding discharge capacities were 120mAh/g and lOOmAh/g at rate of 0.1 C.
Ferric compound and ferrous compound caused different results on the microstructure and electrochemical properties of the LiFePO4 products when they were used as iron source.
Using XRD quantitative method instead of wet chemical in ditenninadon of ferrous compound concentration is of great significance, XRD method not only rapid presise, simple but also the result is more reliable, it displays directly the different phases of ferrous compounds in sinter ore, and will be directly used in control of sinter process.
Particularly, after dehydration at 113°C, the ferric complex is reduced into a ferrous compound, with a quadrupole splitting of 3.89 mm/s, which corresponds to the anhydrous form of K2Fe(ox)2 2 H2O.
It is shown that after dehydration, the ferric complex is reduced into a ferrous compound, with a large quadrupole splitting (3.84 mm/s), which corresponds to the anhydrous form of Rb2Fe(ox)2 6 H2O.
The radiolytic decomposition proceeds as a first-order process due to the original compound depletion and to the radiolytic stability of the ferrous compound.
The radiolytic decomposition proceeds as a first-order process due to the original compound depletion and to the radiolytic stability of the ferrous compound.
Using XRD quantitative method instead of wet chemical in ditenninadon of ferrous compound concentration is of great significance, XRD method not only rapid presise, simple but also the result is more reliable, it displays directly the different phases of ferrous compounds in sinter ore, and will be directly used in control of sinter process.Using XRD method the following three conditions must be fulfilled:(l) Measurement of all ferrous compound phases diffraction intensit...
Nb-doped lithium iron phosphates were synthesized and in-situ carbon coated by one-step solid-state reaction using ferrous compound as the iron source and polypropylene as the reductive agent and carbon source.The results show that the one-step solid-state synthesized Nb doped LiFePO_4/C powders are near-spherical particles of 100 500nm with the olivine type LiFePO_4 structure,and wrapped with carbon nets decomposed from polypropylene.Electrochemical analyses show that LiFePO_4/C with 1.0% Nb(i...
LiFePO_(4) was considered as a new kind of cathode material candidate for lithium ion batteries due to its advantages.LiFePO_(4)/C composites were successfully prepared from Fe_(2)O_(3) via solid state reaction by a thermal reduction method in Ar+5%(volume fraction) H_(2) atmosphere.The crystal structure and electrochemical behavior of the materials were investigated using XRD,SEM,CV and charge/discharge cycle measurements.Based on the results of TGA-DTA,LiFePO_(4)/C composites were synthesized at different...