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s:The reactive amino-silicone fluids were prepared with octamethylcyclotetrasiloxane and N-β-aminoethyl-γ-aminopropylm ethyldimethoxysilane at alkali hydroxide catalyst by condensation.Based on molec ular structure of surfactants and principle of formulation,fatty alcohol polyoxy ethylene ether and alkylphenol polyoxyethylene ether were selected as emulsifyin g agent.The microemulsions of amino-silicone fluid with good stability were pre pared by the revered and aqueous phase emulsifying...

s:The reactive amino-silicone fluids were prepared with octamethylcyclotetrasiloxane and N-β-aminoethyl-γ-aminopropylm ethyldimethoxysilane at alkali hydroxide catalyst by condensation.Based on molec ular structure of surfactants and principle of formulation,fatty alcohol polyoxy ethylene ether and alkylphenol polyoxyethylene ether were selected as emulsifyin g agent.The microemulsions of amino-silicone fluid with good stability were pre pared by the revered and aqueous phase emulsifying technique,and had excellent e ffect while applied to soft treatment of textile.

以八甲基环四硅氧烷和N -β-氨乙基 -γ -氨丙基甲基二甲氧基硅烷为原料 ,碱金属氢氧化物为催化剂 ,通过催化缩合法在 1 0 0℃下反应 4~ 6h ,合成了反应性氨基硅油。并从表面活性剂的分子结构和复配原则出发 ,选择脂肪醇聚氧乙烯醚和烷基酚聚氧乙烯醚作为乳化剂 ,采用逆相和水相乳化法制成了各种稳定性良好的氨基硅油微乳液 ;将其用于织物的柔软整理 ,具有良好的使用效果

This paper expounded the influencing factors in the production and use of amino-modified polysiloxane, including exterior factors: acid or base electrolytes, shearing strength and temperature, and interior factors: raw materials for synthesizing silicone,modification of the group and emulsifier for silicone emulsification. Based on the characteristics of amino-silicone, the approach to improving its stability was given.

阐述了氨基改性有机聚硅氧烷生产和应用中的诸多影响因素.其中,外部因素:酸碱电解质、剪切力、温度;内部因素:合成硅酮的原料、基团的改性、硅酮乳化所用的乳化剂.针对氨基硅酮的特点,提出了改善其稳定性的方法

The water-borne nano-meter complex road-mark coatings are of quick-dry, strong abrasion-resistant, water- resistance and aging-resistance. Cross-linked copolymerizing monomers and amino-silicone coupling agent are selected to co-polymerize with acrylic and styrene monomers through core/ shell emulsion polymerization technology to give core/shell latex of soft shell and hard core. Then the latex is compounded with nano-meter silicon dioxide, functional polyamine polymer, pigment and additives to give...

The water-borne nano-meter complex road-mark coatings are of quick-dry, strong abrasion-resistant, water- resistance and aging-resistance. Cross-linked copolymerizing monomers and amino-silicone coupling agent are selected to co-polymerize with acrylic and styrene monomers through core/ shell emulsion polymerization technology to give core/shell latex of soft shell and hard core. Then the latex is compounded with nano-meter silicon dioxide, functional polyamine polymer, pigment and additives to give environment-protection road- mark coatings with perfect performance, supplying the gap of this kind in China.

通过优选交联共聚单体和氨基硅烷偶联剂等功能单体,与丙烯酸类单体、苯乙烯共聚,采用核壳乳液聚合工艺制备了软壳硬核的核壳性乳液,然后与纳米二氧化硅、功能多胺聚合物、颜填料和助剂等复配,制得了性能优异的环保型路标志涂料,具有干燥速度快、强耐磨、耐水性和耐老化的特性。

 
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