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cyclic voltammetry experiment
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  循环伏安实验
     Cyclic voltammetry experiment shows that the title complex in DMF under goes a quasi reversible one electron redox reaction at E_(1/2)=0.884 V.
     循环伏安实验说明,标题配合物在DMF溶液中在E1/2=0.884V处经历了一个准可逆的一电子氧化还原过程。
短句来源
     Cyclic voltammetry experiment shows the titanium dopant obviously improves the reversibility of charge-discharge reaction.
     循环伏安实验表明,掺钛明显改善充放电反应的可逆性。
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  “cyclic voltammetry experiment”译为未确定词的双语例句
     Data Collecting and Processing System for Cyclic Voltammetry Experiment
     循环伏安法实验数据采集及处理系统
短句来源
     The electrochemical properties of SnO_2 as anode material for Li-ion batteries were studied by the galvanostatic charging-discharging experiments and slow scanning cyclic voltammetry experiment.
     通过恒流充放电和循环伏安(CV)实验,表征了不同结构和颗粒度的纳米SnO2锂二次电池负极材料的电化学性能。
短句来源
  相似匹配句对
     Data Collecting and Processing System for Cyclic Voltammetry Experiment
     循环伏安法实验数据采集及处理系统
短句来源
     The Determination of Diuretics by Cyclic Voltammetry
     利尿剂的循环伏安法检测
短句来源
     In the experiment;
     试验采用单因子随机设计方案。
短句来源
     In the experiment:
     在实验中:
短句来源
     Detection of Ethopabate in feed by cyclic voltammetry
     循环伏安法快速检测饲料中球虫酯
短句来源
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  cyclic voltammetry experiment
The cyclic voltammetry experiment shows that phase transformation can be suppressed considerably by increasing the calcination temperature to 800?°C.
      


WO(OMe)_,WO_2(OEt)_2,and WO_2(OP_r~i)_2 have been prepared by electro- chemical synthesis.The observed order of reactivity in R-OH(R=Me,Et,P_r~)solutions in the electrochemical synthesis of tungsten alkoxides is Me>Et>P_r~i,and optimum support electrolyte was considered is Bu_4NBr.It was shown that tungsten n—butoxide,tungsten al- lyloxide can not be prepared by electroch Ymical synthesis.The properity of thermolysis of products has been investigated by DTA and TG analysis and results show that tungsten alkoxides...

WO(OMe)_,WO_2(OEt)_2,and WO_2(OP_r~i)_2 have been prepared by electro- chemical synthesis.The observed order of reactivity in R-OH(R=Me,Et,P_r~)solutions in the electrochemical synthesis of tungsten alkoxides is Me>Et>P_r~i,and optimum support electrolyte was considered is Bu_4NBr.It was shown that tungsten n—butoxide,tungsten al- lyloxide can not be prepared by electroch Ymical synthesis.The properity of thermolysis of products has been investigated by DTA and TG analysis and results show that tungsten alkoxides decompose direct to the respective oxide,olefin and alcohol.Cyclic voltammetry experiment has been designed to investigate electrochemical behavior of tungsten anode.

通过电化学方法合成了 WO(OMe)_4,WO_2(OE_t)_2,WO_2(OP_r~i)_2三种钨(Ⅵ)的烷氧基化物.确定了在 R—OH(R=Me,E_t,P_r~i)体系中以金属钨为阳极,铂为阴极电解合成钨的烷氧基化物时,其反应的活性依次为 Me>E_t>P_r~i.最佳支持电解质为 Bu_4NBr.证明不能通过电化学合成法制备正丁醇、丙烯醇的钨烷氧基化物.研究了产物的热分解性质,结果表明,钨的烷氧基化物在热解过程中直接分解为 WO_3、烯烃和醇.测定了阳极钨的动电位扫描循环伏安曲线.

Myoglobin undergoes irreversible heterogeneous electron transfer reactions at bare metal electroeds. Thus, much effort has been devoted to obtain quasi-reversible electrochemical reactions of myoglobin at metal electrodes modified with mediators ̄(1~3). However, the electron transfer rates at the above modified electrodes is very small so that the spectroelectrochemical techniques should be used in the most of studies. Recently, Taniguchi et al ̄[4]. reported that a quasi-reversible electrochemical reaction of...

Myoglobin undergoes irreversible heterogeneous electron transfer reactions at bare metal electroeds. Thus, much effort has been devoted to obtain quasi-reversible electrochemical reactions of myoglobin at metal electrodes modified with mediators ̄(1~3). However, the electron transfer rates at the above modified electrodes is very small so that the spectroelectrochemical techniques should be used in the most of studies. Recently, Taniguchi et al ̄[4]. reported that a quasi-reversible electrochemical reaction of the purified horse heart myoglobin was observed at an indium oxide electrode with cyclic voltammetry technique. It was suggested that high purification of myoglobin may be the main reason for obtaining a quasi-reversible electroChemical reaction of myoglobin in the cyclic voltammetry experiments. In this papor, it was reported for the first time that a pair of well-defined redox peaks were oberved in the CV of the commercially available horse heart myoglobin without further purification at an indium oxide electrode after oxygen was eliminated from the solution and the molecules of the oxldized form of myoglobin, i. e.metmyoglobin.

用循环伏安法和同步荧光光谱技术研究了肌红蛋白的电化学行为,实验结果表明,高铁肌红蛋白分子中至少存在一个可调节分子构象变化的氧分子,而且长时间通入高纯氮气可以除掉高铁肌红蛋白分子内的这个氧,当高铁肌红蛋白分子内的氧被彻底除去后,用循环伏安法可以观察到肌红蛋白在三氧化二铟电极上的准可逆的电学反应。同步荧光光谱实验表明,高铁肌红蛋白在彻底除氧后,分子构象发生了变化,而且这种构象变化是可逆的。

The present paper discusses characteristic of electrochemical oxidation of epinephrine at glassy carbon electrode(GCE) in pH3~7 constant ionic strength solution with cyclic voltammetry experiment.The adsorption phenomenon of epinephrine is researched and the saturate surface excess( Γ )and other kinetic parameters of the electrode process are calculated.The result of the experiment indicates that epinephrine is weakly absorbed at the GCE and the saturate surface excess of epinephrine can not...

The present paper discusses characteristic of electrochemical oxidation of epinephrine at glassy carbon electrode(GCE) in pH3~7 constant ionic strength solution with cyclic voltammetry experiment.The adsorption phenomenon of epinephrine is researched and the saturate surface excess( Γ )and other kinetic parameters of the electrode process are calculated.The result of the experiment indicates that epinephrine is weakly absorbed at the GCE and the saturate surface excess of epinephrine can not be negligible in McIlvaine buffer solution whose pH value is more than or equal to three.It is also found through further analysis that the variation of pH value of McIlvaine buffer solution highly affected kinetic characteristic of electrochemicaloxidationofepinephri ne.

探讨了肾上腺素在pH3~7恒离子强度溶液中、玻璃碳电极上的吸附现象,解析了表面超额Γ等一系列电极过程的动力学参数.结果表明:(1)肾上腺素在玻璃碳电极上存在“弱”吸附现象,并且在pH≥3的McIlvaine缓冲溶液中,肾上腺素的吸附量是比较大的;(2)溶液介质pH值的变化对于肾上腺素电化学氧化过程的动力学特征影响较大

 
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