Fe 3+ and other cations are chelated by EDTA,NH 4SCN and (C 4H 9) 4NCl is then added to decompose the Fe-EDTA chelates and the liberated EDTA is back-titrated with In(NO 3) 3 standard the Fe 3+ forms a [(C 4H 9) 4N] 3[Fe(SCN) 6] association compound.
Co(HA_2)_2(H_2O)_2+Ni(HA_2)_2(HA)(H_2O)It has been proved that the selectivity of solvent extraction of cobalt(Ⅱ)and nickel(Ⅱ) depended remarkably on the molecular structure of the extracta-ble chelates.
Using methanol/water(40: 60, V/V) containing 0. 05mol/L phosphate buffer (pH=6. 0) and 0. 01 mol/L TBAP as mobile phase at a flow-rate of 0. 8 ml/min, the chelates were separated completely and detected electrochemically at+0. 9V(vs. SCE).
Chemiluminescence activated by the chelates Eu(tta)3phen and Eu(dbm)3phen in the thermal decomposition of diphenyldiazomethane in benzene in the presence of oxygen was examined at 333 K.
A two-stage procedure is proposed for the immobilization of ion pairs of pyrocatechol azo derivatives and trihydroxyfluorones and their chelates with metal ions on paper.
Chelates of Mo(VI) with tiazolylazopyrocatechol and of Sb(III) with phenylfluorone are used for the test determination of 0.01-1000 mg/L cationic surfactants.
Ammonium phenyldithiocarbamate and ammonium phenylhydrazine-dithiocarbamate havebeen found to be suitable reagents for cupric ions.Their 0. 05% aqueous solutions give withcupric ions dark brown precipitate or coloration.Limit of identification of both reagents is 0. 3γ(concentration limit,1:166,000) ,when tests are performed on spot plate.Bismuth,cobaltous,nickelous,mercurous and silver ions interfere.Among them,Co~(++) and Ni~(++) heavily mask thereaction of Cu~(++).But the chelates of Ni~(++) and Co...
Thirty-two organometallic or organic compounds were tested on the therapeutic effect against schistosomiasis japonica in white mice, rabbits and dogs.In this paper we reported the results of 4 antimony cyclic-mercaptides and 2 corresponding tincompounds and 1 organomercury compounds,3 stibonic acids and related compounds,4 bis(p-aminophenoxy)- thiaalkanes,4 EDTA-chelates of antimony,tin,mercury and bismuth,“TWSb”, hexachloroethane,tetrachloroethylene and some other antimony,tin and mercury compounds. ...
The inorganic salts of antimony, arsenic and bismuth are toxic substances, but their hard dissociated organic derivatives are less toxic and are widely used in the- rapy. Organic chelating compounds such as ethylenediaminetetraacetic acid (I) are often used as agents for detoxification of heavy metals. It appears that complexes formed by therapeutic metals and ethylenediaminetetraacetic acid would be less toxic as well and might be useful therapeutically. Such compounds have been prepared in the present wor...