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amino -
相关语句
  相似匹配句对
     Synthesis of Amino-Polyols
     胺基多元醇的合成
短句来源
     AMINO-SILICONE SOFTENER
     氨基聚硅酮柔软剂
短句来源
     Biogeochemistry of Amino Acids
     《氨基酸生物地球化学》
短句来源
     Uses of Amino Acids
     浅议氨基酸的实际应用
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  amino -
Synthesis and Cytotoxic Activity of 6-(Substituted-Phenyl)Amino-5,8-Quinazolinediones
      
In this example we describe, 3D QSAR studies on phenoxy substituted N-(3-(1,1,2,2-Tetrafluroethroxy)benzyl)-N-3-phenonxyphenyl)-trifluro-3-amino-2-propanols using GFA, CoMFA and CoMSIA.
      
Synthesis and Biological Evaluation of Allosteric A1-Adenosine Receptor Modulators Structurally Related to (2-Amino-4,5,6,7-Tetr
      
A facile and new approach to synthesize 2-amino-4-(4-amoinophenyl)-1H-1,3-diazol-1-yl-alkylaminomethanethiones
      
The approach to the synthesis of novel amino-C-glycosides
      
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p-Nitro-acetophenone was prepared by diazotizing p-amino-acetophenone in fluoroboric acid solution and replacing the diazonium fluoroborate group by the nitro group in presence of finely divided copper as catalyst. Yield 55-60%; m.p. 76-78℃. Recrystallization from alcohol gave a product of m.p. 80℃.

從乙醯苯胺、醋酸酐與氯化鋅作用,經水解後製得對胺基苯乙酮。在氟硼酸水溶液中重氮化之,再在亞硝酸鈉的水溶液中以銅粉為觸媒,將此重氮團置換成爲硝基,即得對硝基苯乙酮。

In connection with our work on “sulfabenzothiazoles”,several tertiary am- inophenyl-thioureas are required.The usual procedure of rearranging substituted ammonium thiocyanates failed to give satisfactory results.They were prepared, according to Douglass and Dains' procedure,by the reaction of benzoyl isothiocy- anate on p-ter.-amino-aniline followed by hydrolyzing the benzoyl thioureas formed.Among the products obtained,p-diethylamino-,p-N-piperidyl- and p-N- morpholinyl-thioureas and most of the intermediates...

In connection with our work on “sulfabenzothiazoles”,several tertiary am- inophenyl-thioureas are required.The usual procedure of rearranging substituted ammonium thiocyanates failed to give satisfactory results.They were prepared, according to Douglass and Dains' procedure,by the reaction of benzoyl isothiocy- anate on p-ter.-amino-aniline followed by hydrolyzing the benzoyl thioureas formed.Among the products obtained,p-diethylamino-,p-N-piperidyl- and p-N- morpholinyl-thioureas and most of the intermediates are new compounds.

用异硫氰化苯醯与对-叔胺基苯胺相作用,得苯醯对-叔胺基苯硫脲。再经水解,即得对-叔胺基苯硫脲。经由此法制得对-二甲胺基苯硫脲,对-二乙胺基苯硫脲,对-(N-六氢吡啶基)-苯硫脲,对-(N-四氢基)-苯硫脲。其中后三者都是新化合物。综合过程中的中间产物,多半也是新化合物。

4-Methyl-5-ethyl-2-thiouracil reacts with ethyl bromide in alcoholic solution in presence of sodium ethylate,forming 2-ethylmercapto-4-methyl-5-ethyl-uracil(m. p.141°),from which 2-ethylmercapto-4-methyl-5-ethyl-6-chloropyrimidine,boiling at 148-150° at 13 mm.,at 164-166° at 17 mm.,or at 180-185° at 25 mm.,is prepared according to the directions given by Johnson and Bailey.This chloro- pyrimidine reacts with sodium methylate in methyl alcohol forming 2-ethyl- mercapto-4-methyl-5-ethyl-6-methoxypyrimidine,boiling...

4-Methyl-5-ethyl-2-thiouracil reacts with ethyl bromide in alcoholic solution in presence of sodium ethylate,forming 2-ethylmercapto-4-methyl-5-ethyl-uracil(m. p.141°),from which 2-ethylmercapto-4-methyl-5-ethyl-6-chloropyrimidine,boiling at 148-150° at 13 mm.,at 164-166° at 17 mm.,or at 180-185° at 25 mm.,is prepared according to the directions given by Johnson and Bailey.This chloro- pyrimidine reacts with sodium methylate in methyl alcohol forming 2-ethyl- mercapto-4-methyl-5-ethyl-6-methoxypyrimidine,boiling at 152-154° at 11 mm., at 156-160° at 16.5 mm.,or at 162° at 22 mm.,and with sodium ethylate in ethyl alcohol forming 2-ethylmercapto-4-methyl-5-ethyl-6-ethoxypyrimidide,boiling at 139-140° at 5 mm.or 142-145° at 7 mm. 2-Ethylmercapto-4-methyl-5-ethyl-6-methoxypyrimidine interacts with chlorine with formation of 2-ethylsulfonyl-4-methyl-5-ethyl-6-methoxypyrimidine,m.p.45- 47°,in a yield of 81% of the theory.2-Ethylmercapto-4-methyl-5-ethyl-6-ethoxy- pyrimidine interacts with chlorine with formation of 2-ethylsulfonyl-4-methyl-5- ethyl-6-ethoxypyrimidine,boiling at 202-205° at 5 mm.or at 212-215° at 10 mm.,in a yield of 91% of the theory.2-Ethyl-mercapto-4-methyl-5-ethyl-6- chloro-pyrimidine interacts with chlorine with formation of 2-ethylsulfonyl-4- methyl-5-ethyl-6-chloro-pyrimidine,m.p.74-75.5°,in a nearly quantitative yield. 2-Ethylsulfonyl-4-methyl-5-ethyl-6-chloro-pyrimidine reacts with sodium methy- late in methyl alcohol,producing 4-methyl-5-ethyl-2,6-dimethoxypyrimidine,boil- ing at 123° at 15 mm.or 113-115° at 11 mm.;while 2-ethylsulfonyl-4-methyl- 5-ethyl-6-methoxypyrimidine reacts with sodium methylate in methyl alcohol, producing the same pyrimidine-dimethyl ether,boiling at 123° at 17 mm.2- Ethylsulfonyl-4-methyl-5-ethyl-6-ethoxy-pyrimidine reacts with sodium ethylate in ethyl alcohol in an analogous manner to form 4-methyl-5-ethyl-2,6-diethoxypyri- midine,which boils at 130° at 8 mm.4-Methyl-5-ethyl-6-methoxy-uracil,m.p. 194-195°,is produced by boiling 2-ethylsulfonyl-4-methyl-5-ethyl-6-methoxypyri- midine with 10% sodium hydroxide solution.Likewise,4-methyl-5-ethyl-6-ethoxy- uracil,m.p.179-180°,is produced by boiling 2-ethylsulfonyl-4-methyl-5-ethyl- 6-ethoxypyrimidine with 10% sodium hydroxide solution.The action of alcoho- lic ammonia upon 2-ethylsulfonyl-4-methyl-5-ethyl-6-chloropyrimidine at 100—105° gives 2-ethylsulfonyl-4-methyl-5-ethyl-6-aminopyrimidine,melting at 108—109°. 4-Methyl-5-ethyl-cytosine,m.p.296-298° or m.p.294°,is formed (i) by boiling 2-ethylsulfonyl-4-methyl-5-ethyl-6-amino-pyrimidine with 6 N hydrochloric acid and (ii) by heating 4-methyl-5-ethyl-6-methoxy-uracil with alcoholic am- monia at 120-140° for 18 hours.Thus,there are two new routes for synthesiz- ing 4-methyl-5-ethyl-cytosine,starting from 2-ethylmercapto-4-methyl-5-ethyl- uracil.Although these new methods involve one or two steps more than the old method described by Johnson and Bailey,who heated 2-ethylmercapto-4-me- thyl-5-ethyl-6-chloropyrimidine with alcoholic ammonia,producing the correspond- ing mercaptoaminopyrimidine,from which the ethylmercapto-group was removed by boiling with hydrochloric acid,they appear to be unique.

(1)2-乙硫醇基-4-甲基-5-乙基-6-氯代嘧啶和醇钠在醇溶液中反应,则生成它相应的乙硫醇-嘧啶-醚类。(2)2-乙硫醇-嘧啶类有下列结构:式中 X 为卤素或烷氧基。它很容易和氯互相作用,形成嘧啶一砜。(3)当2-乙磺醯-嘧啶类和醇钠及碱作用时,则嘧啶中的乙磺酰基在所有的情况下都相似于一个易于被烷氧基和羟基所置换的卤原子。然而氨和氯-乙磺酰-嘧啶反应时,则氯原子为氨基取代,而乙磺酰基仍然是不作用的。(4)叙述了两种新的合成4-甲基-5-乙基-6-氨基-2-氧-嘧啶的方法。

 
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