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mass transfer calculating
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Using multi-phases multi-minerals, multi-composition chemical balance, and the mass transfer calculate theory was developed by Helgeson, according the result of minerals identify in the area-Muyukou, Datong, this paper constructs the mathematical model of mass transfer. Through simulate calculate with the program PHREEQE. We acquired values of solution of primary minerals product of secondary mineral and materials into the water. The calculate results in hydrochemical composition...

Using multi-phases multi-minerals, multi-composition chemical balance, and the mass transfer calculate theory was developed by Helgeson, according the result of minerals identify in the area-Muyukou, Datong, this paper constructs the mathematical model of mass transfer. Through simulate calculate with the program PHREEQE. We acquired values of solution of primary minerals product of secondary mineral and materials into the water. The calculate results in hydrochemical composition and type are correspond with the sample. Meantime, we also studied the mechanism of hydrochemical type zoning and the environment conditions combined with the result of hydrothermal chemistry, simulate and verify the chemical-reaction, element transfer and separation, and mineral series that restrict the hydrochemical zoning.

运用多相、多矿物、多组分化学平衡和Helgeson发展的质量迁移计算理论 ,以大同麻峪口地区为例 ,依据该区岩石矿物鉴定结果 ,建立质量迁移数学模型 ,采用PHREEQE程序 ,模拟计算获得原生矿物溶解量、次生矿物生成量和进入水中的物质量。计算所得地下水化学成分、水化学类型与实际水样分析结果接近 ;结合化学热力学结果研究了水化学类型分带机制和环境条件 ,进而模拟和验证了化学反应、元素迁移和分异 ,以及制约水化学分带的矿物序列。

 
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