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intercalated complex
相关语句
  夹层复合物
     A kaolinite-methanol intercalated complex with inter-spacing of 1.0 nm was synthesized by washing kaolinite with hydrazine monohydrate, 10 mol aqueous solution of urea, and pure methanol successively.
     以水合联胺,10 mol尿素水溶液及甲醇先后与高岭石反应,合成了晶面间距为1.0 nm的高岭石甲醇夹层复合物
短句来源
     Formation of Kaolin-Dimethylsulfoxide Intercalated Complex
     高岭土-二甲亚砜夹层复合物的形成机理
短句来源
  插层复合物
     Rapid Preparation for Kaolinite/Dimethyl Sulphoxide Intercalated Complex Induced by Microwave
     微波诱导快速制备高岭石/二甲亚砜插层复合物
短句来源
     We studied the microwave effect for inserted piece,intercalation rate and intercalation speed,and discussed intercalated complex and action principles of the microwave by fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD),thermogravimetric/differential thermal anaysis(TG/DTA) and transmission electron microscopy(TEM).
     同时使用傅立叶红外光谱(FT-IR)、X射线衍射(XRD)、热重分析(TG/DTA)、透射电镜(TEM)等手段,对插层复合物进行表征,进一步研究微波在反应中的作用;
短句来源
     Watering kaolin-potassium acetate intercalated complex, kaolin is exfoliated into fine slice and the size of grain is less than 2μm.
     水洗清除插层复合物中的醋酸钾后,SEM观察表明高岭土被剥离成细小的鳞片状,粒径小于2μm;
短句来源
  夹层复合体
     SYNTHESIS AND PROPERTIES OF KAOLINITE-METHANOL INTERCALATED COMPLEX
     高岭石–甲醇夹层复合体的合成及其特性
短句来源
     Preparation and characterization of kaolinite-postassium acetate intercalated complex
     高岭石/醋酸钾夹层复合体的制备与表征
短句来源
  “intercalated complex”译为未确定词的双语例句
     SiO_(2)-pillared layered titanate(SiO_(2)-H_(2)Ti_(4)O_(9)) was prepared in this study by intercalating Si-contained polymer into the interlayers of the layered K_(2)Ti_(4)O_(9) and then calcining the intercalated complex.
     采用逐步交换法,将含硅多聚物嵌入到层状钛酸的层间,通过焙烧制得S iO2柱层状钛酸(S iO2-H2Ti4O9)光催化剂.
短句来源
     Reasearch Advances in Kaolinite/Organics Intercalated Complex
     高岭石/有机插层复合材料的研究进展
短句来源
     In this paper,we first induct microwave techniques into research work of preparation for kaolinite/organics intercalated complex.
     首次将微波技术引入到制备高岭石/有机物插层复合材料的研究. 采用微波诱导二甲亚砜(DMSO)对高岭石进行插层,大大缩短了处理时间,且达到了较理想的插层效果.
短句来源
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  intercalated complex
FT-IR analyses of the intercalated complex have established the nature of interactions between the host structures and the incoming DMSO molecules.
      
The intercalated complex has been characterized by X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FT-IR) and thermogravimetric analysis techniques.
      
This arrangement, to some extent, may impart a sieving effect to the intercalated complex for certain smaller organic compounds.
      
Apparently this aliphatic side chain reinforces the stability of the intercalated complex by anchorage into the minor groove.
      


This paper summarized the current developments of the kaolinite/organics intercalation from slecting of the reagents, thermodynamics analysis and factors and characterization of intercalation.The difficults, developed orient and the potential application of kaolinite/organics intercalated complex are introduced.

本文从插层剂的选择、插层过程中的热力学分析与影响因素、结构与性能表征等方面对高岭石 有机插层复合材料的研究现状进行了总结 ,并概述了该领域目前的研究重点及其主要应用前景

A kaolinite-methanol intercalated complex with inter-spacing of 1.0 nm was synthesized by washing kaolinite with hydrazine monohydrate, 10 mol aqueous solution of urea, and pure methanol successively. The complex was unstable at the beginning and under ambient conditions for 72 hrs or the temperature of 105 OC for 2 min, the inter-spacing reduced to 0.85 nm, and further to 0.79 nm under the temperature of 200 OC. It remained unchanged even if the complex was put under the temperature of 300...

A kaolinite-methanol intercalated complex with inter-spacing of 1.0 nm was synthesized by washing kaolinite with hydrazine monohydrate, 10 mol aqueous solution of urea, and pure methanol successively. The complex was unstable at the beginning and under ambient conditions for 72 hrs or the temperature of 105 OC for 2 min, the inter-spacing reduced to 0.85 nm, and further to 0.79 nm under the temperature of 200 OC. It remained unchanged even if the complex was put under the temperature of 300 OC for 24 hrs. The change in inter-spacing under heat treatment and the IR spectra of the resultant 0.85 nm and 0.79 nm intercalates clearly showed presence of methanol in the interspace of the complex. Judging from the expansion value and the minimum diameter of a methanol molecular, only a single layer of the organic molecules was intercalated with a considerable amount of bonds (lower inter-spacing of the intercalates indicating higher extent to which methanol molecules were inserted). It was deduced that methyls were possibly inserted into hexagonal rings of silica tetrahedrons and hydroxyls into octahedrons. Perturbation and shift of infrared absorption bands attributed to hydroxyls in kaolinite structure suggested that interaction between methanol molecule and kaolinite was stronger in 0.79 nm intercalate than in 0.85 nm intercalate.

以水合联胺,10 mol尿素水溶液及甲醇先后与高岭石反应,合成了晶面间距为1.0 nm的高岭石甲醇夹层复合物。复合物不太稳定,在常温下 (约放置72 h) 或1050C加热下 (2 min)晶面间距收缩为0.85 nm。于2000C加热时,晶面间距进一步收缩为0.79 nm。0.79 nm复合物在3000C条件下长时间加热也未再发生变化。由层间膨胀值的大小及甲醇分子的最小厚度推测,0.85 nm及0.79 nm夹层复合体中甲醇分子明显地嵌入了高岭石的结构内部。其甲基可能嵌入了硅氧四面体的六角环空洞中,而羟基嵌入了铝氧八面体内。IR图谱表明0.79 nm复合物中甲醇分子与高岭石的相互作用较之0.85 nm复合物更强。

The potassium acetate is intercalated into layers of kaolin quickly and kaolin-potassium acetate intercalated complex is prepared by grinding the mixture of coal-series kaolin from Datong, Shanxi, potassium acetate and a little water and drying them. At the same time, kaolin is exfoliated rapidly during grading. This method not only shortens intercalation time, but also reduces the quantity of potassium acetate. Watering kaolin-potassium acetate intercalated complex, kaolin is exfoliated into fine...

The potassium acetate is intercalated into layers of kaolin quickly and kaolin-potassium acetate intercalated complex is prepared by grinding the mixture of coal-series kaolin from Datong, Shanxi, potassium acetate and a little water and drying them. At the same time, kaolin is exfoliated rapidly during grading. This method not only shortens intercalation time, but also reduces the quantity of potassium acetate. Watering kaolin-potassium acetate intercalated complex, kaolin is exfoliated into fine slice and the size of grain is less than 2μm. According to the x-ray powder diffraction and the equation of Scherrer, kaolin is exfoliated into two dimensions nano material.

山西大同煤系高岭土与醋酸钾和少量水的混合物经研磨、烘干,不但使醋酸钾分子快速插入高岭土层间,得到了高岭土/醋酸钾插层复合物,而且研磨也促进了高岭土的剥离,缩短了插层时间,减少了醋酸钾的用量。水洗清除插层复合物中的醋酸钾后,SEM观察表明高岭土被剥离成细小的鳞片状,粒径小于2μm;根据XRD图谱,经Scherrer方程计算,表明高岭土被剥离成二维纳米材料。

 
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