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Emission and absorption band spectra of sulphur dioxide were studied in the region between 2600 to 2000 A.U. A new system of emission bands (about 150 bands) was found. When these bands were compared with the absorption bands and Mr. Lotmar's fluorescent bands, coincidences were found which amount to 40% and 50% of the total number of absorption and fluorescent bands respectively. These agreements and the very different structure as compared with the SO bands recorded on the same plate made it very probable...

Emission and absorption band spectra of sulphur dioxide were studied in the region between 2600 to 2000 A.U. A new system of emission bands (about 150 bands) was found. When these bands were compared with the absorption bands and Mr. Lotmar's fluorescent bands, coincidences were found which amount to 40% and 50% of the total number of absorption and fluorescent bands respectively. These agreements and the very different structure as compared with the SO bands recorded on the same plate made it very probable that SO2, is the emitter of these emission bands. Evidences were also found that these emission bands arc not the known bands of O2, Oa+ and S2 in the same region. As a further support a vibra-tional level scheme was worked out, using the three fundamental frequencies of the normal SO2, molecule (1150, 525, and 1360 cm-1) in the lower state and 750 and 350 cm-1 (possible also 1110 cm-1) as the frequencies in the upper state. This scheme accounts for 1Q% of the absorption bands, 70% of the emission bands and a small fraction of the fluorescent bands. While the scheme may not be the final due to the complexity of the vibrational formula, one feels fair, as far as the present evidence goes, to conclude that the emission bands observed are actually emitted by the SO2, molecules and that they can be fitted by a vibrational level scheme based on the three known fundamental frequencies of the normal state.

此文目的在报告二氧化硫气体分子之吸收光谱及发射光谱(emission speetrun)之研究光谱区域约在2000A与2600A间有一新组发射光带(band)发现。数约百五十在吸收光带中有百分之四十之光带与此发射光带附合。在Lotmar先生之弗光光谱(fluorescent speetrum)中,有百分之五十之光带与此发射光带附合并此所得之发射光带之结构与SO之光带显有区别,令人设信此发射光带为SO_2分子所发者。在另一方面,找到证据,所得之发射光带亦非0_2,O_2~+及S_2诸分子之光谱为求更进一步之证实,试以SO_2之三基本振动数(fundamental frequency)1150,525及1360cm~(-1)为能力阶梯之差而作一常态(normal state)下之能力阶梯。再用750,350cm~(-1)(或1110亦用)为分子在激态(excited state)时之振动数,而作一激态下之能力阶梯所得之能力图(energydiagram)可说明吸收光带之70%,发射光带之70%及弗光光带之一小部份,此能力图并不完全,故不能望其为最终者。以三原子分子情形复杂,完全正确之分析,尚有待焉。之 能 力唯协...

此文目的在报告二氧化硫气体分子之吸收光谱及发射光谱(emission speetrun)之研究光谱区域约在2000A与2600A间有一新组发射光带(band)发现。数约百五十在吸收光带中有百分之四十之光带与此发射光带附合。在Lotmar先生之弗光光谱(fluorescent speetrum)中,有百分之五十之光带与此发射光带附合并此所得之发射光带之结构与SO之光带显有区别,令人设信此发射光带为SO_2分子所发者。在另一方面,找到证据,所得之发射光带亦非0_2,O_2~+及S_2诸分子之光谱为求更进一步之证实,试以SO_2之三基本振动数(fundamental frequency)1150,525及1360cm~(-1)为能力阶梯之差而作一常态(normal state)下之能力阶梯。再用750,350cm~(-1)(或1110亦用)为分子在激态(excited state)时之振动数,而作一激态下之能力阶梯所得之能力图(energydiagram)可说明吸收光带之70%,发射光带之70%及弗光光带之一小部份,此能力图并不完全,故不能望其为最终者。以三原子分子情形复杂,完全正确之分析,尚有待焉。之 能 力唯协所得之能 力 圆 山。。。,。w山。…。。。。\可。Z5t 叫 吸收 几 卅之70九传 时 光排 上 7,%及 比 儿 儿 卅上 一 个 部 份 此 能 力 闲 伙 不 正 全;故个能 望IC iX侦相 许 nt原一户 外 广似形 应 输,完全 正雕之分 析。尚有

This is a brief report of the measurements by the method of critical penetration frequency of the maximum intensities of ionization in the ionospheric layers during the partial solar eclipse of June 19, 1936 at Shanghai. The results support the ultra-violet light theory of ionization in the F1 layer. For the E layer these results suggest that a considerable part of the ionization may be due to agents different from ultraviolet light.

本文报告公历一九三六年六月十九日在上海日偏蚀时用临界频率法测量天空电离层游离强度之变化就F_1层所显之结果而论,足为紫外线作用论强有力之一证惟按E层所显之结果则显出该层游离化之主因颇有一部分非紫外线之作用。

The absorption coefficients of β-rays from UX2 and RaE were completely studied. Two outstanding features have been found by the authors: (1) The complete logarithmic absorption curve of rays is not a really straight line but a broken one consisting of several segments of straight lines which intersected at a certain point. The slopes of the segments are greater as the absorbing screens are thicker. (2) The values of the absorp-tion coefficients are not constant but can be varied according to the surrounding...

The absorption coefficients of β-rays from UX2 and RaE were completely studied. Two outstanding features have been found by the authors: (1) The complete logarithmic absorption curve of rays is not a really straight line but a broken one consisting of several segments of straight lines which intersected at a certain point. The slopes of the segments are greater as the absorbing screens are thicker. (2) The values of the absorp-tion coefficients are not constant but can be varied according to the surrounding conditions of measurement. Among the conditions, the substance beneath the preparation Or the reflector, the substance encircles the preparation or the screen support, and the distance between the active preparation and the ionisation chamber window are the three main determinating tactors which influence the variation of the coefficient.

自UX_2及RaE放出之β射线之吸收系数经实验后得下列结果:(1)吸收图为数段直线所合成,厚吸收片者坡度较陡。(2)吸收系数随三种因素而改变,一为承受放射物之性质与厚薄,一为围绕放射物之圆管,一为放射物与游离箱之距离。

 
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