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coupled cl reaction
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  “coupled cl reaction”译为未确定词的双语例句
     A new highly sensitive method of chemiluminescence(CL) is presented in this paper for the determination oftrace rhodium by the coupled CL reaction of Mn(Ⅱ)-BrO ̄-_3-luminol in the presence of Rh(Ⅲ).
     本文基于Rh(Ⅲ)对Mn(Ⅱ)-BrO ̄-_3反应的催化作用,并与luminol的化学发光反应相偶合,建立了一种测定铑的高灵敏度化学发光新方法。
短句来源
     The method has been satisfactorily applied to determine free oxalic acid in diethyl oxalate and oxalate in human urine, A coupled CL reaction echanism is presented.
     方法用于草酸二乙酯和人体尿液中草酸的测定,获得满意的结果.
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  相似匹配句对
     Cl.
     Cl.
短句来源
     Chemiluminescence Analysis with Coupled Reaction
     偶合反应化学发光分析
短句来源
     ; Cl.
     Cl.
短句来源
     Investigation into Conditions of Chemical Coupled Reaction
     化学偶联反应条件探析
短句来源
     The mechanism of the CL reaction was also discussed.
     并对其可能的反应机理进行了探讨。
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A new highly sensitive method of chemiluminescence(CL) is presented in this paper for the determination oftrace rhodium by the coupled CL reaction of Mn(Ⅱ)-BrO ̄-_3-luminol in the presence of Rh(Ⅲ).The kineticcurve of the CL svstem has been modelled and the cond-itions for determining Rh(Ⅲ)by the developeped CLmethod have been investigated and optimized.Foreign ionsand other noble metal ions can be separated by trioctylamine(TOA)extraction chromatography.The concentra-tion range of linear response...

A new highly sensitive method of chemiluminescence(CL) is presented in this paper for the determination oftrace rhodium by the coupled CL reaction of Mn(Ⅱ)-BrO ̄-_3-luminol in the presence of Rh(Ⅲ).The kineticcurve of the CL svstem has been modelled and the cond-itions for determining Rh(Ⅲ)by the developeped CLmethod have been investigated and optimized.Foreign ionsand other noble metal ions can be separated by trioctylamine(TOA)extraction chromatography.The concentra-tion range of linear response is from 1×10 ̄(-5) to 10μg/mL,and the detection limit is 5 × 10 ̄(-6) μg/mL.Themethod has been used to determine trace rhodium withsatisfactory results.

本文基于Rh(Ⅲ)对Mn(Ⅱ)-BrO ̄-_3反应的催化作用,并与luminol的化学发光反应相偶合,建立了一种测定铑的高灵敏度化学发光新方法。研究并优化了测定铑的条件,研究了外来离子的影响,配合三正辛胺(TOA)萃取色谱法分离干扰离子。铑浓度在1×10 ̄(-5)~10μg/mL范围内与化学发光峰高成直线关系,检测限(3σ)达到5×10 ̄(-6)μg/mLRh。方法用于贵金属离子混合液的活性炭载体催化剂中铑的测定,获得满意结果。

A new method of chemiluminescence (CL) is presented for the determination of trace rhodium by the coupled CL reaction of polassium chlorate-polassium iodide-rhodium.CL method has been investigated and optimized. The detection limit is 3. 8×10-6 μg/mL Rh, and the concentration range of linear response is from 1×10-5~1 μg/mL Rh. Foreign ions and other nobl metal ions can be separated by trioctyl amine(TOA)extraction chromatography.The method has been used to determine trace rhodium in mixture...

A new method of chemiluminescence (CL) is presented for the determination of trace rhodium by the coupled CL reaction of polassium chlorate-polassium iodide-rhodium.CL method has been investigated and optimized. The detection limit is 3. 8×10-6 μg/mL Rh, and the concentration range of linear response is from 1×10-5~1 μg/mL Rh. Foreign ions and other nobl metal ions can be separated by trioctyl amine(TOA)extraction chromatography.The method has been used to determine trace rhodium in mixture solution of nobl metals ions with satisfactory results.

研究了Rh(Ⅲ)催化KClO3-KI的反应与I2-Luminol的化学发光反应相偶合,建立了测定痕量铑的化学发光新方法.对测定条件进行了优化,此方法具有较高的灵敏度,检测限达到3.8×10-6μg/mLRh;线性浓度范围宽,为1×10-5~1μg/mLRh.采用三正辛胺(TOA)萃取色谱柱将铑(Ⅲ)分离出来,方法已用于测定贵金属离子混合液中的铑

Reactions of 16 organic acids with Ru(phen)32+ (phen= 1,10 - phenanthroline) and Ce (IV) were examined for chemiluminescence(CL)light emission. Organic acids with C = O or OH group were found capable of increasing the CL light emission. CL intensity were linearly related to the concentration of them. The method has been satisfactorily applied to determine free oxalic acid in diethyl oxalate and oxalate in human urine, A coupled CL reaction echanism is presented.

本文以16种有机酸为研究对象,系统地研究了钌(Ⅱ)-邻菲咯琳-有机酸-Ce(Ⅳ)偶合化学发光反应.结果表明,化学发光强度与含有羰基或羟基的有机酸的浓度在一定浓度范围内具有良好的线性关系,据此建立了羰基和羟基羧酸的化学发光分析法,提出了偶合化学发光反应机理.方法用于草酸二乙酯和人体尿液中草酸的测定,获得满意的结果.

 
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