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|  | | 为了更好的帮助您理解掌握查询词或其译词在地道英语中的实际用法,我们为您准备了出自英文原文的大量英语例句,供您参考。 | |
The driving force behind the rules of the valence shell electron pair repulsion model
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A chief tenet of VSEPR (valence shell electron pair repulsion theory) is that very electronegative atoms or groups attached to a central atom pull electrons toward themselves.
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The structures of complex anions of Pb(II) coordination compounds (complexonates) with monoamino-, diamino-, and polyaminopolycarboxylic acids as ligands were interpreted in terms of a model of the valence shell electron pair repulsion.
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Diagram and describe the shape of a covalently bonded pure silicon molecule using the valence shell electron pair repulsion theory.
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| | On the basis of the Valence Shell electron Pair repulsion theory, we have justified bond angles in AB_(4-n) molecules depend on the bond parameter Z~(*2)/r_k of thebonding atoms A and B. Formulas for calculation of the bond angles of AX_3 and AH_(4-n) molecules of the VA、VIA group elements are proposed and extended. | | 本文在价层电子对互斥理论的基础上,证明了AB_(4-n)型分子键角的大小与键合原子A和B的键参数Z~(*2)/r_k有关。导出了计算VA、VIA族元素AX_3和AH_(4-n)型分子键角的公式,并加以推广。 | | 文摘来源 | | Using a modified Gasteiger's method for calculation of atomic charges in molecules and the partial equalization of orbital electronegativity model (PEOE) the PEOE electronegati vities of bonding atoms in halides of Group V elements were calculated. A linear relation ship between molecular bond angles and the PEOE electronegativities was obtained, and the variations of the bond angles were explained in a systematic way.In this paper the quantitative aspect of the Valence-Shell #... | | 本文根据物理模型对Gagsteiger计算分子中原子电荷的方法加以修改后,计算了V族元素卤化物分子中原子成键时的部分均衡轨道电负性值(PEOE),并将该值与各分子键角值相关获得了定量的线性关系,求得了解析表达式。通过计算着重分析研究了V族元素卤化物分子的键角与电负性的关系,对它们的键角变化规律作出了较为系统的解释。本文揭示了VSEPR理论所具有的定量基础,并进一步预测了目前尚未能测定几何构型的一些砹化物分子的键角值。 | | 文摘来源 | | In this paper, the dilemma of five-coordination in Valence-shell electron-pair repulsion ( VSEPR ) is discussed . | | 本文主要讨论了价电子互斥理论VSEPRT在解释五配位化合物构型时的困境。 | | 文摘来源 | |   | | << 更多相关文摘 |
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