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silylidyne insertion reaction
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  “silylidyne insertion reaction”译为未确定词的双语例句
     On the basis of quantum chemical study of the silylidyne insertion reaction with HCl, the statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the thermodynamic functions, the equilibrium constants A factor and the rate constants of this reaction in the temperature range 200~2000K.
     在量子化学对SiH与HCl反应计算的基础上 ,运用统计热力学和Wigner校正的Eyring过渡态理论计算了该反应在 73 .1 5~ 1 873 .1 5K温度范围内的热力学函数、平衡常数、频率因子A和速率常数随温度的变化 .
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  相似匹配句对
     Thermodynamic and Kinetic Studies on Silylidyne Insertion into HCl Reaction
     次甲基硅SiH与HCl反应的热力学及动力学性质研究(英文)
短句来源
     Quick insertion sort
     快速插入排序法
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     Circular Insertion Sort
     循环插入排序法
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On the basis of quantum chemical study of the silylidyne insertion reaction with HCl, the statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the thermodynamic functions, the equilibrium constants A factor and the rate constants of this reaction in the temperature range 200~2000K. The calculation results show that the SiH insertion reaction into HCl is thermodynamically dominant at low temperature and kinetically favored at higher...

On the basis of quantum chemical study of the silylidyne insertion reaction with HCl, the statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the thermodynamic functions, the equilibrium constants A factor and the rate constants of this reaction in the temperature range 200~2000K. The calculation results show that the SiH insertion reaction into HCl is thermodynamically dominant at low temperature and kinetically favored at higher temperature. The statistical thermodynamic calculation shows that this reaction is exothermic and of entropy decrease at 73.15 ~ 1873.15K. The kinetic calculation results indicate that this reaction obeys the Arrhenius rate law, and the rate constant of this reaction increases with increasing temperature.

在量子化学对SiH与HCl反应计算的基础上 ,运用统计热力学和Wigner校正的Eyring过渡态理论计算了该反应在 73 .1 5~ 1 873 .1 5K温度范围内的热力学函数、平衡常数、频率因子A和速率常数随温度的变化 .计算结果表明该反应在低温下具有热力学优势 ,而在高温下具有动力学优势 .该反应在研究的温度范围内是一放热、熵减少的反应 ,反应的速率常数随温度的升高而增大 ,而且服从Arrhenius定律 .

 
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