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Five phases were determined by means of quantitative EPMA, SEM, X-ray diffraction, etc. in the high Ti-slag with high Mg and Ca contents, smelted by 6000 kVA electric furnace. The principal phase is the anosovite solid solution of Ti_3O_5 type in amount of 87.06% of the slag. Along the grain interfaces of the solid solution phase, CaO concentrated mainly in the form of 2CaO·TiO_2. This is the phase area so called the crystal phase enriched Ca and Mg. Most MgO is collected in the glass phase which is about... Five phases were determined by means of quantitative EPMA, SEM, X-ray diffraction, etc. in the high Ti-slag with high Mg and Ca contents, smelted by 6000 kVA electric furnace. The principal phase is the anosovite solid solution of Ti_3O_5 type in amount of 87.06% of the slag. Along the grain interfaces of the solid solution phase, CaO concentrated mainly in the form of 2CaO·TiO_2. This is the phase area so called the crystal phase enriched Ca and Mg. Most MgO is collected in the glass phase which is about 10.90% of the slag. Other two minor phases are found to be Ti-Fe alloy and metallic Fe. Thus, the calculated structural formula of such an anosovite in the slag seems to be: 0.15[(Mg_(0.27)Ti_(0.73))0.2TiO_2]·0.85[Ti_2O_3·TiO_2] 高镁、钙的高钛渣经查明有5个相。高钙、镁富集区结晶相化合物为2CaO·TiO_2,玻璃相中富集MgO。黑钛石固溶体含MgO很低,只占渣中MgO总量的11.65%,MgTi_2O_5/Ti_3O_5的分子比为1∶24。导出了渣中黑钛石的分子式为0.15[(Mg_(0.27)Ti_(0.73))0.2TiO_2]·0.85[Ti_2O_3·TiO_2]。 This paper deals with the compostion of pasty boronization of steel with protective coating. The composition which is optimized has a good result of protection, low price and wide resource. By means of x-ray diffract ometer, the authors study the structure of phase with protective coating which is agglomerated in high temperature and find that this protective coating is made up of glass phase,SiO_2, CrO_3 and pyroxenite. The soffening point of protective coating and the production of glass phase... This paper deals with the compostion of pasty boronization of steel with protective coating. The composition which is optimized has a good result of protection, low price and wide resource. By means of x-ray diffract ometer, the authors study the structure of phase with protective coating which is agglomerated in high temperature and find that this protective coating is made up of glass phase,SiO_2, CrO_3 and pyroxenite. The soffening point of protective coating and the production of glass phase which changes with the temperature is observed by means of GX_A-high temperature physical properties instru mentation. The protective coating begins to soften about at 700℃; the glass phase begins to produce at 800℃ and remains stable until 950℃. According to the experiment ,the efficient minimal thickess of the protective coating is 1. 2 mm. 本研究对膏剂渗硼用保护涂层的组成进行了优选,优选出的配方保护效果良好,涂层材料价廉易得,来源广。用x-射线衍射仪对保护涂层在高温烧结后的物相进行了观测和分析,确定该涂层为玻璃相和SiO_2,Cr_2O_3、透辉石(CaMg[Si_2O_6])等品相所组成。用GX_A型高温物性测试仪对涂层的软化和玻璃相的生成随温度变化的依存关系进行了观测,观察到涂层约在700℃开始软化,800℃时玻璃相开始形成,在950℃下玻璃相能稳定存在而不发生流淌。在本试验条件下,计算得出保护涂层起有效保护作用的最小厚度应为1.2mm。 The CeO2 modified SrTiO3 ceramics were prepared by conventional ceramic process. The SrTiO3 matrix and CeO2 additive were combined in following system:SrTiO3 +x(CeO2·TiO2), where x is the weight percent , of which x (wt%)=2,5, 10, 15, 20,25, and 30. The samples were sintered at 1400℃ for an hour in air. The Ce element in SrTiO3 ceramics is used as an impurity donor. The scanning electron microscopic (SEM) analysis and X-ray diffractive examination of SrTiO3 ceramics containing CeO2 indicated that there exists... The CeO2 modified SrTiO3 ceramics were prepared by conventional ceramic process. The SrTiO3 matrix and CeO2 additive were combined in following system:SrTiO3 +x(CeO2·TiO2), where x is the weight percent , of which x (wt%)=2,5, 10, 15, 20,25, and 30. The samples were sintered at 1400℃ for an hour in air. The Ce element in SrTiO3 ceramics is used as an impurity donor. The scanning electron microscopic (SEM) analysis and X-ray diffractive examination of SrTiO3 ceramics containing CeO2 indicated that there exists a Ce2O3 secondary phase (viz. glass phase) and it had solid solution solubility for impurities which decrease the semiconductive property of SrTiO3 ceramics , and weaken the oxidation of the surface of grain and thus increase the conductivity of the grains. The semiconducting ceramics process lightly distorted cubic structure at room temperature. This paper mainly gives a study of the conductivity of CeO2 modified SrTiO3 ceramics. ConductivityofCeO_2ModifiedSrTiO_3CeramicsXiaoMingshan;WangChengjian;ChenLing;ZhangChengju;WangXixiang(DepartmentofPhysics,Sha...
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