The laser beam from a pulsed tunable dye laser is tuned to the resonance line of sodium 3~2S_(1/2)-3~2P_(1/2)((?) =16961cm~(-1)) to excite the sodium atoms in a hydrogen-acetylene flame.
A new title macrocycle L and its complex [NaClO4·L]2 have been synthesized and characterized. The crystal structure of the complex shows that two L direct coordinate two sodium atoms,rcspectively,and two perchloraec μ2-O bridges make them form a sandwich dimeric structure unit.
This paper reports the experimental observation of the higher states' fluorescence changing with laser power,which was populated through energy polling collisions between two excited sodium atoms excited to the first excited state by a CW single mode laser in sodium vapor.
It indicates that the three silicon atoms,which are in the same trigonal plane of the most stable structure with D3h symmetry for Si5 cluster,have surplus bonding abilities. Thus,they can bond with three hydrogen,lithium,and sodium atoms and six hydrogen atoms to form four stable compounds,i.
Sodium is thus sensitively detected by nonresonance fluorescence induced by saturated excitation of sodium atoms produced by the laser beam. The detection limit reached is 10~(-11) g/ml.
e. ,Si5H3,Si5H6,Si5Li3,and Si5Na3.Although the hydrogen,lithium,and sodium atoms are in the same main group,they bond with the silicon atoms of the Si5 cluster by different ways,and the additions also have various influences on the trigonal bipyramid structure of Si5.
The interatomic interaction potentials derived from new precision spectroscopic data are used to calculate averaged collision cross sections of two sodium atoms.
The observed high-speed clouds of sodium atoms are assumed to have been formed through ionization, ion acceleration by the bidirectional electric fields of Alfvén waves in the Io-Jupiter current tube, and their neutralization.
The crystal structure of sodium tetraselenite has a monoclinic unit cell with a=5.90A, b=4.82A, c=10.19A, β = 91°20', which contains 2 {NaH3(SeO2)2}. The space group is Gs2-Pn.The equatorial Weissenberg photograph h0l indicates that the projection of the structure onto the plane (010) has a pseudo plane group p6m and a pseudo unit cell with a' = 5.94A, b'=5.90A, r' = 119°50'. The pseudo plane group helped to fix the selenium and sodium atoms in the projection (Figure 1) and the Patterson p...
We investigated the near resonant scattering and collision induced fluorescence of sodium atoms with doublet excited states in a weak laser field. By changing the frequency of the incident light and measuring the integral intensities of the components of the scattered light, the near resonant excitation cross-section of each sublevel was obtained as functions of the frequency detuning. Their variations are qualitatively explained by the interaction potential between the sodium atom and var...
A few analytical expressions for the observables in a quantum beat experiment is derived, which can be used to describe the experimental results and to obtain the fs splitting in sodium D states. The, change of the n2D states of sodium atoms in a weak electric field is also discussed.