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transfer thermodynamic functions
相关语句
  迁移热力学函数
     TRANSFER THERMODYNAMIC FUNCTIONS OF HCI FROM H_2O TO DMSO-EtOH-H_2O
     盐酸从水到DMSO—EtOH—H_2O混合溶剂的迁移热力学函数
短句来源
     Transfer thermodynamic functions of potassium tetrophenlborate from water to water/2-propanol mixtures
     四苯硼钾由水到水-异丙醇的迁移热力学函数
短句来源
  相似匹配句对
     CRITERIONS FOR THERMODYNAMIC OPTIMIZATION OF HEAT TRANSFER SYSTEM
     传热系统的热力学优化准则
短句来源
     Thermodynamic Analysis and Application of Convective Heat Transfer
     对流换热过程的热力学分析及其应用
短句来源
     TECHNOLOGY TRANSFER
     山东省高新技术转移中心项目推荐
短句来源
     TECHNOLOGY TRANSFER
     山东省高新技术转移中心推荐项目
短句来源
     Thermodynamic Functions of Transfer of Naphthalene from Water to Water- t-butyl Alcohol Solutions
     萘由水到水-叔丁醇混合溶剂的迁移热力学函数
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In this paper,Emf's of the cell(A):pt,H_2(101.3KPa)|HCl(m),DMSO(x),EtOH(y),H_2O|Δgcl-Ag,were measured at ethanol 10,20,30%(wt)when concentrations of DMSO were fixed respectivelyin 10 and 20(wt)% from 298.15 to 318.15K.By using least square regression method the standardelectromotive forces were calculated.Futhermore,the transfer Gibbs free energe,enthalpy and entropywere calculated.In terms of the exprimental data of the transfer thermodynamic functions,themicro-structure of the electrolyte solution was...

In this paper,Emf's of the cell(A):pt,H_2(101.3KPa)|HCl(m),DMSO(x),EtOH(y),H_2O|Δgcl-Ag,were measured at ethanol 10,20,30%(wt)when concentrations of DMSO were fixed respectivelyin 10 and 20(wt)% from 298.15 to 318.15K.By using least square regression method the standardelectromotive forces were calculated.Futhermore,the transfer Gibbs free energe,enthalpy and entropywere calculated.In terms of the exprimental data of the transfer thermodynamic functions,themicro-structure of the electrolyte solution was also discussed.

本文采用电动势法测定了无液体接界电池Pt,H_2(101.3KPa)|HCl(m),DMSO(x),EtOH(y),H_2O|AgCl-Ag的电动势。其中当DMSO的含量分别恒定在x=10.20%(wt)时,EtOH的含量分别取y=10、20、30%(wt),温度区间为298.15~318.15k;温度间隔为5K.根据实验测得的电动势,计算了迁移热力学函;发现当DMSO%(wt)恒定时,ΔG_t~0与EtOH%(wt)有线性关系,而ΔH_t~0和TAS_t~0随EtOH%(wt)的改变,都有最高点出现。并据此讨论了溶液的微观结构。

Solubilities of RbBPh4 in water, methanol, ethanol, 1 - propanol, 1 - butanol, 1 -pentanol , 1 - hexanol , 1 - hepanol and 1 - octanol at 288 . 15 ~ 328 . 15K have been determined by spectrophotometry. The standard transfer thermodynamic function of RbBPh4 from water to straight - chain alkanols at 288. 15 ~ 328. 15K has been calculated. The results can be experssed asFurthermore, the contribution of microscopic interaction to the standard Gibbs energy of transfer of RbBPh4 was calculated and discussed....

Solubilities of RbBPh4 in water, methanol, ethanol, 1 - propanol, 1 - butanol, 1 -pentanol , 1 - hexanol , 1 - hepanol and 1 - octanol at 288 . 15 ~ 328 . 15K have been determined by spectrophotometry. The standard transfer thermodynamic function of RbBPh4 from water to straight - chain alkanols at 288. 15 ~ 328. 15K has been calculated. The results can be experssed asFurthermore, the contribution of microscopic interaction to the standard Gibbs energy of transfer of RbBPh4 was calculated and discussed.

在288.15~328.15K下,用光度法测定RbBPh_4在直链一元醇中的溶解度.计算并讨论RbBPh_4由水至直链一元醇中的标准迁移热力学函数,经微机曲线拟合给出△_(tr)G-w→s,△_(tr)S_w→s随温度及碳原子数的经验关系:△_(tr)G_w→s=-20.3504+6.6005×10~(-5)T~2+(14.6628lgn)/(1-7.7713×10~(-9)T~3)△_(tr)S_(w→s)=-0.1320T-(3.4185×10~(-4)T~2lgn)/(1-7.7713×10~(-9)T~3)~2用Born模型及单层结构模型对标准迁移自由能变化规律进行定性与定量的解释.

 
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