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thermokinetic study
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  热动力学性质
     Determination of Reaction Heat and Thermokinetic Study on the Extraction of Co(Ⅱ) with HEH[EHP] in Kerosene from Sulfate Solution
     HEH[EHP]从硫酸介质中萃取钴的反应热测定和热动力学性质
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     Thermokinetic Study on the Fire Retardant Wood
     木材阻燃的热动力学研究
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     Cell Kinetic Study─Ⅲ.Thermokinetic Study of Bacterial Arithmetic Series Growth
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     Thermokinetic Study of Mitochondrial External Metabolism
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     Thermokinetic Study on the Inhibition Against Arginase Catalyzed Reaction by NaF
     NaF抑制精氨酸酶催化反应的热动力学研究
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     Thermokinetic Study on the Growth Process of Halobacterium Halobium
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     Of Study
     论读书
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     The study was
     研究了ABS和PVC对PC/ABS共混体系力学性能的影响。
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     STUDY OF BACTERIAL GROWTH ON ITS THERMOKINETIC
     细菌生长的热动力学研究
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     THE THERMOKINETIC STUDY OF WOOD PYROLYSIS
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  thermokinetic study
A thermokinetic study of the clathration of isomeric xylenes by the Ni(NCS)2 (4-methylpyridine)4 host
      


According to the heating effect caused by interaction between matters,a series of experiments on the interaction between drugs and cells from human bodies,DNA and physiological saline have been carried out with a MS-80 standard Calvet microcalorimeter.The experiments include: (1) Thermokinetic studies of the effect of anticancer drugs [sodium norcantharidate (ASN),the bioac- tire materials (Sp.P and Sp.S) from algae etc.]on the cancer cells [Hela,human breast carcinoma (Bcap-37),human adenocarcinoma gastric...

According to the heating effect caused by interaction between matters,a series of experiments on the interaction between drugs and cells from human bodies,DNA and physiological saline have been carried out with a MS-80 standard Calvet microcalorimeter.The experiments include: (1) Thermokinetic studies of the effect of anticancer drugs [sodium norcantharidate (ASN),the bioac- tire materials (Sp.P and Sp.S) from algae etc.]on the cancer cells [Hela,human breast carcinoma (Bcap-37),human adenocarcinoma gastric cells (SGc-7901 and MCF-7) etc.] and the normal cells from human bodies [diploid fibroblasts from human fetal lung (2BS) etc.] at 310.15 K:(2) Studies of the in- tercalation binding of some alkaloidal drugs with the bioactivity to inhibit monoamine oxidase (harmalinc and harmine etc.) to call thymus DNA in neutral aqueous solution at 298.15 K:(3) Studies of the interaction between long acting drugs (long acting oral contraceptive-norgestrel etc.) and slow- releasing drug (Contac) and aqueous solution of 0.9% NaCI at 310.15 K.All the experimental results have given their characteristic thermograms and the interaction enthalpy changes.On the analysis of all the results,the authors put forward a method on application of microcalorimetric technique for screen- ing and examination of medicines.The principle of application and the experimental operation of this method have been expounded,and some results of the above experiments have been discussed.As one of the methods for screening and examining medicines,the microcalorimctric method has some distin- guished features and advantages over other methods.

基于物质间相互作用时存在的热能效应,几年来,本文用 MS-80标准型Calvet 微量量热计进行了一系列药物与人体细胞某些生物大分子相互作用的热动力学实验。这些实验包括:1.抗癌药物(去甲斑蟊酸钠[ASN],螺旋藻活性提取[Sp.P]和[Sp.S]等)以癌细胞(宫颈癌传代细胞[Hela])、人乳腺癌细胞[Bcap-37]和[MCF-7]、人胃癌细胞[SGc-7901]等)以及正常人体细胞(人体胚肺二倍体细胞[2BS]等)作用的热动力学研究;2.具有抗单胺氧化酶活性的生物碱类药物(骆驼篷碱[HL]、去氢骆驼篷碱[HM]等)在水溶液中对小牛胸腺 DNA 嵌插结合及其焓变的研究;3.长效医药(长效避孕药-复方甲基炔诺酮[HQ]等)和缓释医药(康太克[Contac]-复方盐酸苯丙醇胺)与生理盐水(0.9%的氯化钠水溶液)作用的研究。所有的实验结果都给出了各自的特征热动力学图谱及相互作用的焓变。通过实验结果的分析和总结,作者提出了将微量量热技术用于筛选和检验医药的新方法。文章中阐述了方法实施的科学依据,同时简单叙述了实验的过程及操作,并对实验结果进行了一些必要的讨论,与其他筛选和检验医药的方法相比,微量量热法有其明显的...

基于物质间相互作用时存在的热能效应,几年来,本文用 MS-80标准型Calvet 微量量热计进行了一系列药物与人体细胞某些生物大分子相互作用的热动力学实验。这些实验包括:1.抗癌药物(去甲斑蟊酸钠[ASN],螺旋藻活性提取[Sp.P]和[Sp.S]等)以癌细胞(宫颈癌传代细胞[Hela])、人乳腺癌细胞[Bcap-37]和[MCF-7]、人胃癌细胞[SGc-7901]等)以及正常人体细胞(人体胚肺二倍体细胞[2BS]等)作用的热动力学研究;2.具有抗单胺氧化酶活性的生物碱类药物(骆驼篷碱[HL]、去氢骆驼篷碱[HM]等)在水溶液中对小牛胸腺 DNA 嵌插结合及其焓变的研究;3.长效医药(长效避孕药-复方甲基炔诺酮[HQ]等)和缓释医药(康太克[Contac]-复方盐酸苯丙醇胺)与生理盐水(0.9%的氯化钠水溶液)作用的研究。所有的实验结果都给出了各自的特征热动力学图谱及相互作用的焓变。通过实验结果的分析和总结,作者提出了将微量量热技术用于筛选和检验医药的新方法。文章中阐述了方法实施的科学依据,同时简单叙述了实验的过程及操作,并对实验结果进行了一些必要的讨论,与其他筛选和检验医药的方法相比,微量量热法有其明显的特点及优越性。

A self-function recursion equation, can be obtained after theperfect nonlinear funtion, has been transformed. Through treatingthe self-function recursion equation with the theory of regression analysis, a novel researchmethod for the kinetics of chemical reactions, self-function regression method, has been de-veloped. This method can be applied not only to thermokinetic studies, but also to ultravio-let spectrophotometry for treating kinetics of complex reactions. As a result of treating ther-mogram...

A self-function recursion equation, can be obtained after theperfect nonlinear funtion, has been transformed. Through treatingthe self-function recursion equation with the theory of regression analysis, a novel researchmethod for the kinetics of chemical reactions, self-function regression method, has been de-veloped. This method can be applied not only to thermokinetic studies, but also to ultravio-let spectrophotometry for treating kinetics of complex reactions. As a result of treating ther-mogram equation of the first order reaction with Laplace transform, the thermogramequation can be expressed as . The rate constant of the first order reaction,k1, and the cooling constant of thermokinetic system, k, can be obtained at the same timewith the self-function regression method. In order to test the validity of this method, thesaponifications of ethyl acetate and ethyl butyrate have been studied at 25℃ in aqueous solu-tion. The rate constants calculated with this method are in agreement with th0se in litera-tures, and therefore the self-function regression method is correct in deed.

由完全非线性函数经变换得到自函数递推方程.根据回归分析理论,建立了一种化学反应动力学研究法──自函数回归法.应用该法在25℃水溶液中研究了乙酸乙酯和了酸乙酯的皂化反应的动力学常数.

The recent progress in the thermokinetic studies of the chemical reaction by conduction calorimeter was reviewed in this paper. The main attention was paid on dynamic method and thermal flux method and their applications in the chemical and biological fields, Fifty-four references were included in this summary.

综述了用热导式热量计研究化学反应热动力学的最新状况,重点评述了动态法和热流法及其在化学与生物领域中的应用

 
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