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chemisorption mechanisms
相关语句
  化学吸附过程机理
     A study on the adsorption characteristics of the chemisorption refrigeration working pair using SrCl_2 as adsorbent and NH_3 as refrigerant was performed. The adsorption isotherms were obtained,the adsorption isotherm equations were fit and the chemisorption mechanisms were discussed.
     对以SrCl2 为吸附剂、NH3 为致冷剂所组成的化学吸附式制冷工质对的吸附性能进行了研究 ,得到了吸附等温线、回归出吸附等温方程并对化学吸附过程机理进行了探讨。
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  相似匹配句对
     On Mechanisms
     机制论
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     The mechanisms were postulated.
     本文对此种关系的可能机制进行了初步推测。
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     Physisorption and Chemisorption
     物理吸附与化学吸附
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  chemisorption mechanisms
Cadmium is possibly retained by electrostatic and chemisorption mechanisms by thepillared montmorillonite whereas electrostatic attraction ismainly responsible for Cd sorption by unpillared montmorillonite.
      


The chemisorption of CO on NiO( l 00)has been investigated by means ofSCC-DV-Xa embedded cluster motiel calculations.Counterooise method has been introducedto eliminate the BSSE.After a comnarison betxveen the electrostatic effects and the orbitaleffects,a more detailed understanding of the CO/NiO( 1 00)chemisorption mechanism isobtained.The calculation results demonstrate tl1at:1)the adsorption geometry of C atom atop acation site perpendicularly is most preferabie;2)the interaction between CO and...

The chemisorption of CO on NiO( l 00)has been investigated by means ofSCC-DV-Xa embedded cluster motiel calculations.Counterooise method has been introducedto eliminate the BSSE.After a comnarison betxveen the electrostatic effects and the orbitaleffects,a more detailed understanding of the CO/NiO( 1 00)chemisorption mechanism isobtained.The calculation results demonstrate tl1at:1)the adsorption geometry of C atom atop acation site perpendicularly is most preferabie;2)the interaction between CO and NiO(100 )surface is mainly electrostatic,which accounts for the adsorption-induced blueshift of C-Ostretching frequency.

采用SCC-DV-Xa嵌入簇模型方法,研究了CO/NiO(100)吸附体系。比较表面电场作用与轨道作用对CO性质的影响,并考虑到BSSE校正,对CO在NiO(l00)面上的吸附行为有了较深入的认识。计算结果表明:CO以C端垂直吸附于表面阳离子吸附位;CO与表面的作用主要为静电作用,表面电场作用是使得吸附态CO的IR峰蓝移的主因。

After being treated by shock wave, the defects increased and F color centers formed on crystal MgO were detected by ESR technique. Plausible chemisorption mechanism of F color centers were proposed. Using crystal MgO catalyst treated by shock wave, higher productivity and selectivity of propy-lene were obtained.

ESR研究表明结晶氧化镁经冲击波处理后可产生大量晶格缺陷,并形成F心。用冲击处理后的结晶MgO作丙烷脱氢反应催化剂,丙烷的转化率、丙烯的产率及选择性均有一些提高.初步讨论了可能的结构模型和催化机理.

A study on the adsorption characteristics of the chemisorption refrigeration working pair using SrCl_2 as adsorbent and NH_3 as refrigerant was performed.The adsorption isotherms were obtained,the adsorption isotherm equations were fit and the chemisorption mechanisms were discussed.The results showed that SrCl_2-NH_3 is an excellent working pair in its large adsorption refrigeration capacity per unit weight of adsorbent and suitable for solar energy and low grade waste heat.

对以SrCl2 为吸附剂、NH3 为致冷剂所组成的化学吸附式制冷工质对的吸附性能进行了研究 ,得到了吸附等温线、回归出吸附等温方程并对化学吸附过程机理进行了探讨。研究结果表明 ,SrCl2 NH3 工质对的吸附制冷量大 ,适宜太阳能或低品位余热驱动 ,是性能优良的工质对。

 
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