The aims are to dissertate the methods of how to control the degree of isotacticity when using N -type catalyst to manufacture the polypropylene, as well as influence factors. The research results are the scale of isotacticity is wider when using N--type catalyst than using CS-lone,and more easy to adjust. It can satisfied with manufacturing various brands and standards products, is suitable for manufacturing high and moderate quality polyprpylene.
N-type catalyst was successfully applied in the tri-reactor continuous process (SPG) polypropylene (PP) plant,involving liquid-phase bulk polymerization in vertical reactor and gas-phase bulk polymerization in horizontal reactor. The data indicates that the catalyst completely suitable for SPG process PP plant.
Results showed that the yield of undecenoic acid was up to 24.6% and that of heptaldehyde to 18.3% in presence of N catalyst and at 400°C and 23.3 kPa pressure, 700 g/h flow rate.
The development and application of domestic PP catalysts is introduced, focusing on development trends, characteristics and application fields of N catalyst in the recent years. Suggestions for the improvement of existing PP facilities are also raised.
This paper analyzed the physical and mechanical properties of propylene homopolymers synthesized with N catalyst in different commercial plants. The correlation between physical properties and molecular conformation of the propylene homopolymer prepared with high efficiency N catalyst was discussed.
The results indicate that the propylene homopolymer produced with N catalyst possesses high stereoregularity; this character ensures the resin to be suitable for manufacturing fiber and make the resin be an appropriate base material for physical and chemical modification of polyolefin.
The aluminoxanes and the normal activators, such as triethylaluminum (TEA), triisobutylaluminum (TBA) and MAO were used as cocatalyst for MgCl2-supported Ziegler-Natta catalyst including N and DQ catalyst in propylene polymerization at the temperatures ranging from 70 to 100℃.
Four kinds of polypropylenes (PP) prepared with different catalysts (NPP, GPP, TPP and LPP) were compared in their powder stability, melt processing stability, thermal aging stability and radiation stability. The experimental results verified that the stability of these PP resins was quite different from each other, and the PP made with NPP was the best one among them.
The industrial application of N-type and CS-Ⅱtype catalysts in a 70 kt/a polypropylene plant was introduced. The factors influenced the product quality in appearance,composition and acivity of both catalysts were presented. The characteristics and the difference between N-type and CS-Ⅱ type catalysts in industrial operation and some problems were analyzed and the improvement suggestion was given.
The application of N - type and CS-Ⅱ type catalyst in the 70 000t/a polypropylene plant of SINOPEC Jingmen petrochemical works was introduced in detail. The difference between two catalysts, the characteristics in practical operation and some problems were analyzed in detail. Some suggestions for improvement were also given.
DTA experiments in the air flow and O2 temperature-programmed pulse reaction (TPPR) showed that the optimal oxidation temperature for the Mo2N catalyst was under 450°C because of its instability at high temperature in the presence of O2.
Based on the characteristics of the catalyst-N,a commercial experiment is carried out on catalyst-Ns performance of isotacticity adjustment.During the test period,a smooth operation prevailed,turning out qualified product biaxial-oriented polypropylene product with an isotacticity of 94%~97%.
Compared with similar catalysts in the world, N catalyst has special characteristics in reactivity, orientation and reactivity life. The aging resistance, thermal stability and radiation resistance of products polymerized with the catalyst are all better than those polymerized with other similar catalysts. The development and application of domestic PP catalysts is introduced, focusing on development trends, characteristics and application fields of N catalyst in the recent years. Suggestions for the impr...