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转移电子数
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  transfer electron number
     A Spectroelectrochemical Cell was made successfully from cut sections of Reticulated Vitreous Carbon (RVC). Normal Potential E~(0′) and Transfer Electron Number n of redox system K,Fe(CN)_6/K_3Fe(CN)_6 was determined with this Optically Transparent Electrodes.
     本文采用多孔玻碳切片作为电极材料,制作成功玻碳光透电极,并以K_4Fe(CN)_6K_3Fe(CN)_4作为氧化还原体系,测定了式量电位E°′与转移电子数n。
短句来源
  “转移电子数”译为未确定词的双语例句
     Consumption of oxygen and shifted electrons were calculated to certify the different reactions occured.
     通过氧消耗计算和转移电子数的分析,说明甲烷在电池阳极发生不同类型的反应。
短句来源
     It was determined that the match ratio of complex compound was 1:2.
     经实验测定 ,其配合物的配合比为 1∶2 ,电极反应转移电子数为 3.9。
短句来源
     The resalt showed that the number of electron exchange on charging and discharging was 1.35 according to our approximate calculation, and its theoretical discharge capacity was 393.26 mAh/g, so it has high electrochemical capacity.
     通过对非晶态氢氧化镍样品电极过程极化曲线的测试,计算其交换电流密度和极限电流密度,并根据计算结果,估算出非晶态氢氧化镍作为电极活性材料在充放电过程中电极反应转移电子数近似为1.35,理论放电比容量为393.26mAh/g,表明具有较高的电化学容量。
短句来源
  相似匹配句对
     In addition to the number of electrons transferred in the reaction was caculated.
     求得了电极反应的电子转移为 2 ;
短句来源
     The Determination of Electron Transfer Number in Electrode Reaction
     电极反应中电子转移的测定
短句来源
     Single Electron Transfer Reactions
     单电子转移反应
短句来源
     SINGLE ELECTRON TRANSFER AND NITRATION REACTION
     单电子转移和硝化反应
短句来源
     Measurement of E~0' and n Values by Optically Transparent Thin-Layer Electrochemical Cells
     用光透薄层电池测定式电极电势和电子转移
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A Spectroelectrochemical Cell was made successfully from cut sections of Reticulated Vitreous Carbon (RVC). Normal Potential E~(0′) and Transfer Electron Number n of redox system K,Fe(CN)_6/K_3Fe(CN)_6 was determined with this Optically Transparent Electrodes.

本文采用多孔玻碳切片作为电极材料,制作成功玻碳光透电极,并以K_4Fe(CN)_6K_3Fe(CN)_4作为氧化还原体系,测定了式量电位E°′与转移电子数n。

In this paper the electrochemical and spectroelectro-chemical properties of difluorogermanium porphyrin and dihydroxidegermanium porphyrin have been studied by the cyclic voltammetry and in situ UV-visible spectro-electrochemistry. The results have shown:in the potential window of DMF,the porphy rinring may be reduced in two steps that are reversible . The half-wave potentials for TPPGe(OH)2 are more negative than TPPGeF2,and there are a widespread red shift for the UV-Visible spectum. One electron is transferred...

In this paper the electrochemical and spectroelectro-chemical properties of difluorogermanium porphyrin and dihydroxidegermanium porphyrin have been studied by the cyclic voltammetry and in situ UV-visible spectro-electrochemistry. The results have shown:in the potential window of DMF,the porphy rinring may be reduced in two steps that are reversible . The half-wave potentials for TPPGe(OH)2 are more negative than TPPGeF2,and there are a widespread red shift for the UV-Visible spectum. One electron is transferred in all electrode reactions.To TPPEGeF2,the standard,electrode potentials of first and second reduce react.To TPPGeF2,the standard electrode potentials of first and second reduce reaction are -1.292V and -1.803V,to TPPGe(OH)2,-1. 443V and -1.890V respectively

利用循环伏安和现场紫外光谱电化学方法研究了标题配合物的电化学和光谱电化学性质。结果表明:在DMF介质的电位窗口内,卟啉环发生两步可逆的还原反应;与TPPGeF2相比,TPPGe(OH)2还原的半波电位较负,其紫外光谱吸收峰位置普遍红移;电极反应转移的电子数皆为1;对于TPPGeF2,两步还原的标准电极电位分别为-1.292V和-1.803V,对于TPPGe(OH)2。分别为-1.443V和-1.890V.

The determination of germanium was done on polarograph, in which HClO 4 was taken as support electrolyte, and gallic acid as complexing agent. The results showed that the best determination system was composed by 0.1 mol/L HClO 4 and 5.0×10 -4 mol/L gallic acid. The linear range of germanium determination was 2.0×10 -6 ~5.0×10 -5 mol/L. Through a series of experiments, it was proved that the polarograph wave formed in this system was a complexing adsorption wave. It was determined that the match...

The determination of germanium was done on polarograph, in which HClO 4 was taken as support electrolyte, and gallic acid as complexing agent. The results showed that the best determination system was composed by 0.1 mol/L HClO 4 and 5.0×10 -4 mol/L gallic acid. The linear range of germanium determination was 2.0×10 -6 ~5.0×10 -5 mol/L. Through a series of experiments, it was proved that the polarograph wave formed in this system was a complexing adsorption wave. It was determined that the match ratio of complex compound was 1:2.

以HClO4为支持电解质 ,没食子酸为络合剂 ,在示波极谱仪上对锗进行了测定。实验确定的最佳测定体系是 0 .1mol/LHClO4加 5 .0× 10 -4mol/L没食子酸的体系。锗测定的线性范围是 2 .0× 10 -6~ 5 .0× 10 -5mol/L。通过一系列实验证明了该体系形成的极谱波为配合吸附波。经实验测定 ,其配合物的配合比为 1∶2 ,电极反应转移电子数为 3.9。

 
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