When the sulfonyl fluorides, R_FCFXCF_2OCF_2CF_2SO_2F (5b,2b,8,9) were treated with cobaltic trifluoride, SO_2 was eliminated, and the fluoroalkanes R_FCFXCF_2OCF_2CF_3 (7, 10～12) were obtained.

The increment of the cost-effect ratiosΔC/ΔE 1 for group A and B were—22.27and—8.06respectively; ΔC/ΔE 2 were—3.92,—1.33respectively,as compared with group C.

Interaction energy of the Watson-Crick A-T base pair is -13.90 and -10.24 kcal/mol at B3LYP/6-31G** and HF/6-31G** levels, respectively.

For the examined series of surfactants, the increment of ΔGm due to one methylene group is -4.44 kJ/mol.

The electrode exhibits the slope of the electrode function is -(26 ±1) mV/pc and provides the determination of 1 × 10-5-5 × 10-2 M lead in the pH range 2.75-5.0.

We prove that if an automorphism group of a cyclically ordered set is -transitive, then it is simple.

The total charge is -4 in pKW301 ArsR and +2 in R64 and R733 ArsRs.

In this paper the general synthesis problem of optimal control systems with the criterion of transient responses as a positive integral functional (3) is discussed.In the first part it is assumed that the motion of controlled object is described by a system of ordinary differential equations and that the final states of the system form a bounded and closed convex region in n-dimentional euclidian phase space. A method is proposed for finding all optimal control functions which lead any starting state into the...

In this paper the general synthesis problem of optimal control systems with the criterion of transient responses as a positive integral functional (3) is discussed.In the first part it is assumed that the motion of controlled object is described by a system of ordinary differential equations and that the final states of the system form a bounded and closed convex region in n-dimentional euclidian phase space. A method is proposed for finding all optimal control functions which lead any starting state into the given final region of states. Some conclusions are obtained from the maximum principle by using transversal conditions of optimal trajectories in terminal points, and the particular properties of the stated problem are pointed out. The case of linear dif-ferential equations with integral quadratic functional criterion is investigated in detail.Further, in the second part the fundamental properties of isoloss regions, the rela-tions between the isoloss region and optimal control functions are indicated. As a direct result a partial differential equation determining the optimal loss-function J (x) is found and the connection between function J (x)and optimal vector control function u (x) is also stated. The methods proposed are practically the extension of the me-thods used by us for designing time optimal control systems as seen in [5, 6 ,7].Finally, an example is illustrated with optimal trajectories shown in phase plane.The necessary numerical data is calculated by an analog computer with high accuracy.

Emission and absorption band spectra of sulphur dioxide were studied in the region between 2600 to 2000 A.U. A new system of emission bands (about 150 bands) was found. When these bands were compared with the absorption bands and Mr. Lotmar's fluorescent bands, coincidences were found which amount to 40% and 50% of the total number of absorption and fluorescent bands respectively. These agreements and the very different structure as compared with the SO bands recorded on the same plate made it very probable...

Emission and absorption band spectra of sulphur dioxide were studied in the region between 2600 to 2000 A.U. A new system of emission bands (about 150 bands) was found. When these bands were compared with the absorption bands and Mr. Lotmar's fluorescent bands, coincidences were found which amount to 40% and 50% of the total number of absorption and fluorescent bands respectively. These agreements and the very different structure as compared with the SO bands recorded on the same plate made it very probable that SO2, is the emitter of these emission bands. Evidences were also found that these emission bands arc not the known bands of O2, Oa+ and S2 in the same region. As a further support a vibra-tional level scheme was worked out, using the three fundamental frequencies of the normal SO2, molecule (1150, 525, and 1360 cm-1) in the lower state and 750 and 350 cm-1 (possible also 1110 cm-1) as the frequencies in the upper state. This scheme accounts for 1Q% of the absorption bands, 70% of the emission bands and a small fraction of the fluorescent bands. While the scheme may not be the final due to the complexity of the vibrational formula, one feels fair, as far as the present evidence goes, to conclude that the emission bands observed are actually emitted by the SO2, molecules and that they can be fitted by a vibrational level scheme based on the three known fundamental frequencies of the normal state.

Measurement of the intensity of total scattering of x-rays by a number of polyatomic gases was made for scattering angles between 15° and 130 ° using an ionization method of recording the scattered intensity. Balanced filters of ZrO2, and SrO were used to separate the MoKa rays and Soller slits were placed in front of the ionization chamber to obtain a definite scattering angle. The gases studied are CL2, CO2, N2O, H2S, CC14 and CHCl3. In each case the absolute values of the scattered intensity were determined...

Measurement of the intensity of total scattering of x-rays by a number of polyatomic gases was made for scattering angles between 15° and 130 ° using an ionization method of recording the scattered intensity. Balanced filters of ZrO2, and SrO were used to separate the MoKa rays and Soller slits were placed in front of the ionization chamber to obtain a definite scattering angle. The gases studied are CL2, CO2, N2O, H2S, CC14 and CHCl3. In each case the absolute values of the scattered intensity were determined by comparison with the scattering from oxygen, the results of Wollan for the latter gas being taken as correct. The experimental results are actually compared with Woo's theory of the scattering of x-rays by polyatomic gases and the agreement seems to be satisfactory.