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电子转移理论
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  theory of electron transfer
     In this paper, the theory of electron transfer process proposed by prof. R·A·Marcus——1992 Nobel prize winner, is introduced briefly.
     本文扼要地介绍了1992年诺贝尔奖获得者Marcus教授所提出的电子转移理论
短句来源
     This paper discusses :1. the main ideas of Marcus' theory,2. calculation of inverted area by applying Marcus' theory, 3. the new progress of the theory of electron transfer reaction.
     本文讨论(1)Marcus理论大意:(2)Marcus理论对倒置区域的预测; (3)电子转移理论的进展。
短句来源
     This paper discusses the main ideas of Marcus' theory,calculation of inverted area by applying Marcus' theory and the new progress of the theory of electron transfer reaction.
     讨论了Marcus理论大意,其理论对倒置区域的预测及电子转移理论的进展
短句来源
     Based on the semiclassical theory of electron transfer, quantum chemical calculations at HF/DZP level were performed for the study of intramolecular electron transfer between parallel benzene and benzene cation radical.
     基于半经典电子转移理论 ,结合量子化学计算 ,在 HF/DZP水平上 ,研究外电场作用下平行的苯分子 -苯正离子自由基体系 (C6 H4) + 2 的分子内电子转移问题 .
短句来源
  “电子转移理论”译为未确定词的双语例句
     Theoretical Study on Electron Transfer of Organic Small Molecular
     有机小分子的电子转移理论研究
短句来源
     Theoretical Study on the Photoinduced Intramolecular Electron Transfer in Solvents for Some Typical Systems
     溶剂中几种典型体系分子内光诱导电子转移理论研究
短句来源
     The mechamism of the reaction was shown and analysed by the theories of front orbit and single-electron transfer.
     并运用前线轨道理论及单电子转移理论,对目前争论较多的该反应的机理作了分析、介绍
短句来源
     One of the main achievements of Marcus electron-transfer theory is the predictions of the existence of normal and inverted regions.
     Marcus电子转移理论的主要成果之一是预言了电子转移反应反转区的存在.
短句来源
     The other is application of the electron transfer theory in the new fields.
     尽管Marcus 电子转移理论已经取得了极大成功,但理论本身尚存在许多不完善的地方,需要进一步开展创新性的研究。
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  相似匹配句对
     The Theory of Electron Transfer Reaction and Its Progress
     电子转移反应理论及其进展
短句来源
     The Theory and its Progress of Election Transfer Reaction
     电子转移反应理论及其进展
短句来源
     The Theoretical Calculation for Modulation Transfer Function of Transferred-Electron Photocathode
     转移电子光阴极调制传递函数的理论计算
短句来源
     Theoretical Investigation on Photoinduced Electron Transfer and Solvent Effect
     光诱导电子转移及溶剂效应的理论研究
短句来源
     Theoretical Study on Electron Transfer of Organic Small Molecular
     有机小分子的电子转移理论研究
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  theory of electron transfer
Theory of electron transfer reactions in blue-copper proteins
      
The kred values were strongly at variance from those expected from the free energy change ΔGred of the reaction within the framework of the Marcus' theory of electron transfer.
      
In a previous paper (S Fletcher, J Solid State Electrochem 11:965, 2007) a non-Marcus theory of electron transfer was developed, with results applicable to the normal region of thermodynamic driving forces.
      
The quenching factors are estimated by using Marcus theory of electron transfer reactions.
      
A Theory of Electron Transfer in Bridged and Supramolecular Systems
      
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The hydrocracking reaction of n-hexane (n-C_6) containing 0, 0.05 (m%)or 0.5 (m%) of sulfur on several Pd-HZSM-5 catalysts was studied in a continuous flow pressure microreactor-chromatography. The zeolite catalysts were prepared by cation-exchange, dealumination and finally by ion-exchange with 0.5 (m%) of Pd. The total acidity, Bronsted and Lewis acidity of the catalysts were measured by the IR technique.

在压力连续微反色谱装置上,用无硫正已烷(n-C_6)、含硫0.05(m%)和0.5(m%)的n-C_6作原料,在用阳离子交换、脱铝和交换上0.5(m%)Pd的几种Pd-HZSM-5催化剂上进行加氢裂化反应,同时用红外光谱法测定催化剂的总酸、B酸和L酸.试验结果表明,不含Pd的HZSM-5在无硫n-C_6的反应中具有最高的活性和裂化选择性,但在含硫的n-C_6的反应中具有最低的活性和裂化选择性:几种Pd-HZSM-5催化剂中,总酸和B酸较强的PZ-3和PZ-4具有较高的硫稳定性,同时用电子转移理论讨论了酸性和硫稳定性之间的关系;工业加氢裂化催化剂R-100活性较低,但具有较高的异构化选择性.

In this paper, the theory of electron transfer process proposed by prof. R·A·Marcus——1992 Nobel prize winner, is introduced briefly. Some fundamental aspects and the importance of this theory are emphasized.

本文扼要地介绍了1992年诺贝尔奖获得者Marcus教授所提出的电子转移理论。对该理论的重要意义及基本概况作了简要的说明。

The conversion yield and quantum yield of photoinduced isomerization of dimethy1 N-(p-toluenesulfony1) 7 aza bicyclo[2.2.1]2,5 heptadiene 2,3 dicarboxylate(NNBD),with crystal violet and acridine orange as sensitizers, had ben measured. Based on the fluorescence spec tra and fluorescence quenching of the photasensitizers by NNBD,the reaction mechanism of electron transfer ismerization was tentatively proposed.

本文以结晶紫、吖啶橙为光敏化剂,以N—对甲苯磺酰基-7-氮杂-双环[2.2.1]-2,5-庚二烯-2,3-二羧酸二甲酯(NNBD)为反应底物,测定了NNBD光敏异构化反应的转化率及量于产率。通过荧光谱和NNBD对敏化剂的荧光猝灭试验,根据weller电子转移理论对NNBD的光敏异构化机理进行了探讨。

 
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