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With the aid of ~(13)C--NMR spectra of liquid polyoutadiene(PB), catalytically synthe-sized by Co(Nap)_2 -Al(i-Bu)_3 -PhCCl_3, some terminal structures of PB Ⅰ-Ⅵ and twobranch structures ⅩⅥ and ⅩⅦ have been identified, providing valuable informationfor chain initiation mechanism. On the basis of branch structure the number averagemolecular weight of samples was calculated and compared with the result obtained fromVPO measurement.The ~(13)C NMR spectra of PB modified by α-olefine reveal that α-ole-fine only modifies... With the aid of ~(13)C--NMR spectra of liquid polyoutadiene(PB), catalytically synthe-sized by Co(Nap)_2 -Al(i-Bu)_3 -PhCCl_3, some terminal structures of PB Ⅰ-Ⅵ and twobranch structures ⅩⅥ and ⅩⅦ have been identified, providing valuable informationfor chain initiation mechanism. On the basis of branch structure the number averagemolecular weight of samples was calculated and compared with the result obtained fromVPO measurement.The ~(13)C NMR spectra of PB modified by α-olefine reveal that α-ole-fine only modifies the molecular weight of the polymer, it does not copolymerize withbutadiene. 本文研究了Co(Nap)_2-Al(i-Bu)_3-PhCCl_3催化体系合成的液体聚丁二烯(PB)的~(13)C-NMR谱以及α-烯烃调节分子量的PB~(13)C-NMR谱,观察到TPB的端基结构,据此探讨了链引发机理,证明了α-烯烃是PB分子量的调节剂。根据化学位移计算和分子量测定结果,确认PB存在支化结构,并探讨了支化机理。 The synthesis of liquid polybutadiene was studied by using n-butyllithu-mdiglycoldimethylether-potassium alkalioxides as initator system.The effect of toluene, o-xylene, m-xylene, p-xylene and ethylbenzene as solvent and chain transfer agent on telomerization of butadiene were investigated.The apparent rate constant and the activation energy for propagation, the constant of chain transfer, the apparent rate constant of chain transfer, the activation energy of chain transfer and the times of chain transfre were... The synthesis of liquid polybutadiene was studied by using n-butyllithu-mdiglycoldimethylether-potassium alkalioxides as initator system.The effect of toluene, o-xylene, m-xylene, p-xylene and ethylbenzene as solvent and chain transfer agent on telomerization of butadiene were investigated.The apparent rate constant and the activation energy for propagation, the constant of chain transfer, the apparent rate constant of chain transfer, the activation energy of chain transfer and the times of chain transfre were obtained.The results show that different aromatic chain transfer agents have effect on molecular weight but no effect on microstructure and molecular weight distribution of telomer. 以正丁基锂-烷氧基钾-二乙二醇二甲醚为引发体系合成液体聚丁二烯,考察了以甲苯及邻、间、对二甲苯和乙苯作链转移剂(兼作溶剂)对调聚反应的影响。实验获得了表现增长速度常数、增长活化能,并考察了它们对丁二烯调聚物分子量的影响,同时得到了在一定条件下的链转移常数、链转移速度常数和转移活化能,测得了在相同条件下的链转移次数。不同芳烃链转移剂对调聚物的微观结构有一定影响。 89-I is the liquid disinfectant synthesized by certain technique. pH = 3.25, Specific gravity =1.005, UV spectrum λmax345nm. The quantity of effective component is 5.73±0.05 mg/ml. It is stable. The reserve rate was 97.04% after 8 months. The disinfection efficiency were 99.9999-100% for Escherichia coli 8099, Staphylococcus aureus ATCC 6538, Staphylococcus albus 8032 with 3 ppm of this disinfectant. The effect of temperature(4℃), pH value (9), and organic substance ( 15% bovine serum ) on this disinfectant... 89-I is the liquid disinfectant synthesized by certain technique. pH = 3.25, Specific gravity =1.005, UV spectrum λmax345nm. The quantity of effective component is 5.73±0.05 mg/ml. It is stable. The reserve rate was 97.04% after 8 months. The disinfection efficiency were 99.9999-100% for Escherichia coli 8099, Staphylococcus aureus ATCC 6538, Staphylococcus albus 8032 with 3 ppm of this disinfectant. The effect of temperature(4℃), pH value (9), and organic substance ( 15% bovine serum ) on this disinfectant was little. LD50is 750.7mg/Kg, The Ames test, micronu-clear test, and SCE test were negative. 89-Ⅰ型消毒剂是采用一定工艺合成的液体消毒剂。pH=3.25,比重=1.005,UV光谱λmax345nm,用碘量法测定有效成份为5.73±0.05mg/ml。本品保存稳定,8个月后的保存率为97.04%。对大肠杆菌8099、金黄色葡萄球菌ATCC 6538、白色葡萄球菌8032,采用3ppm的89-Ⅰ,去除率99.9999~100%。在温度(4℃)、pH_9、有机物质15%对消毒效果影响小。毒性小,使用安全,LD50为750.7mm/kg,Ames试验、微核试验、SCE试验阴性。
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